Why homologous proton don't split signal of each other in proton nmr?

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SUMMARY

The discussion centers on the behavior of homologous protons in proton NMR (Nuclear Magnetic Resonance) spectroscopy, specifically why equivalent protons do not split each other's signals. It is established that each proton generates its own magnetic field, but equivalent protons can align their spins in a synchronous manner, leading to a singlet state (S=0) and triplet states. The presence of a magnetic field causes the triplet states to split into three distinct lines, while transitions between singlet and triplet states are weak for nearly equivalent protons, resulting in the "roof effect" where two intensive lines are closely spaced and two weaker lines are further apart.

PREREQUISITES
  • Understanding of proton NMR spectroscopy
  • Knowledge of spin states and coupling in quantum mechanics
  • Familiarity with magnetic fields and their effects on protons
  • Basic concepts of singlet and triplet states in quantum physics
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  • Study the principles of quantum mechanics related to spin and magnetic fields
  • Learn about the "roof effect" in NMR spectroscopy
  • Explore the differences between singlet and triplet states in detail
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Chemists, particularly those specializing in organic chemistry and NMR spectroscopy, as well as students and researchers looking to deepen their understanding of proton interactions in magnetic fields.

Ahmed Abdullah
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Each proton has it's own magnetic field so it should effect the magnetic field of all nearby proton whether it is homologous (equivalent) or not. I don't understand how this discrimination arise?
How a proton understand - "that proton is like me so I shoudn't ... ... ... " I mean it's ridiculous. In organic chemistry textbooks it says that, non-equivalent proton split signal because they can align either toward or against the magnetic field of a given proton. Now I don't understand why it should only apply to non-equivalent protons? Not to equivalent protons?
I am not really getting it. Please help me.
Can anyone explain the theory, please?
 
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Is it possible that homologous or equivalent protons are somehow connected with each other in the sense that they all change orientation in synchronous fashion and can't do it independently from each other?
 
Of course the protons see the field of each other. Consider two equivalent protons. As the coupling commutes with total spin, I can combine the two spins into a siglet state (S=0, spins anti-parallel) and 3 triplet states (spins parallel). Without magnetic field, the triplet states will be degenerate but their energy will be different from the energy of the singlet state, because in the triplet state, the spins are parallel while they are anti-parallel in the singlet state.
Swiching on the magnetic field, the triplet will be split up into 3 with M=-1, 0 , 1 which are equidistant. The radiofrequency can only induce transitions within the triplet, so that you only see one line. However, if the two protons are slightly different, then there can also be transitions from the singlet (M=0) to the triplet states with M=+1 and -1.
However these two lines will be very weak for nearly equivalent protons. Also the two transitions within the triplet from M=0 to M=1 and from M=-1 to M=0 will not be exactly degenerate, because the singlet state and the M=0 state of the triplet will "repell" each other. If you try to figure out the situation, you will see that it describes the "roof effect", i.e. two nearly degenerate intensive lines and two lines which are further off and which are very weak.
 

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