A matrix is not invertible when its determinant is zero because the determinant indicates how the volume of a geometric shape changes under transformation. A zero determinant implies that the transformation squashes the shape into a lower dimension, making it impossible to uniquely map back to the original points. For example, a 2x2 matrix with a determinant of zero collapses a unit square into a line segment, losing information about the original points. Algebraically, if the product of two matrices equals the identity matrix, their determinants must also multiply to one, indicating neither can be zero. Therefore, a zero determinant leads to an undefined inverse, confirming the matrix's non-invertibility.