Why is activity of solvated components equal to 1?

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SUMMARY

The discussion centers on the activity of solvated components in the reaction involving nickel ions and hydrogen sulfide. The textbook states that the activities of the aqueous components, specifically ##a_\mathrm{Ni^{2+} (aq)}## and ##a_\mathrm{2H^{+} (aq)}##, are both equal to 1. This is justified by the definition of activity as the ratio of concentration to standard concentration, where standard state conditions can be achieved in a solution. The confusion arises from the expectation of a different product, NiS(s), rather than a mixture of elements.

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  • Understanding of chemical equilibrium and reaction dynamics
  • Familiarity with the concept of activity in solutions
  • Knowledge of standard state conditions in thermodynamics
  • Basic principles of aqueous chemistry and solubility
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  • Learn about standard state conditions and their implications in chemical reactions
  • Explore the principles of solubility product (Ksp) and its applications
  • Investigate the role of concentration in determining chemical activities
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Homework Statement


Consider the following reaction

$$\mathrm{Ni^{2+}_{(aq)} + H_2S_{(g)} \to Ni_{(s)} + S_{(s)} + 2H^{+}_{(aq)}}$$

What are the activities of the terms in the reaction?

Homework Equations



The activity is defined as ##a = c/c^\circ## in ##\mathrm{ mol \, dm^3}##

3. The Attempt at a Solution


I do not understand why textbook gives ##a_\mathrm{Ni^{2+} (aq)} =1## and ##a_\mathrm{2H^{+} (aq)} =1##: how can I say that those activities are ##1##? Is there a rule to understand activites of solvated compontents (aq)?
 
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It is not always possible, but you can rather easily prepare a solution containing Ni2+ and H+ in such concentrations that their activities equal 1. Makes sense as it is a standard state used as a reference point.

Something is wrong here, but it is hard to judge without a context. I would expect NiS(s) as a product, not mixture of elements.
 

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