Why is activity of solvated components equal to 1?

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The discussion revolves around the activities of solvated components in the reaction between Ni²⁺ and H₂S, specifically questioning why the activities of Ni²⁺ and H⁺ are given as 1. It is clarified that the activity is defined as the concentration relative to a standard state, which can be achieved under certain conditions. The standard state for aqueous solutions allows for activities of certain ions to be considered as 1 when their concentrations are adjusted accordingly. There is confusion regarding the expected products of the reaction, as the participant anticipates NiS instead of elemental products. Understanding the context and definitions of activity is crucial for interpreting these values correctly.
crick
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Homework Statement


Consider the following reaction

$$\mathrm{Ni^{2+}_{(aq)} + H_2S_{(g)} \to Ni_{(s)} + S_{(s)} + 2H^{+}_{(aq)}}$$

What are the activities of the terms in the reaction?

Homework Equations



The activity is defined as ##a = c/c^\circ## in ##\mathrm{ mol \, dm^3}##

3. The Attempt at a Solution


I do not understand why textbook gives ##a_\mathrm{Ni^{2+} (aq)} =1## and ##a_\mathrm{2H^{+} (aq)} =1##: how can I say that those activities are ##1##? Is there a rule to understand activites of solvated compontents (aq)?
 
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It is not always possible, but you can rather easily prepare a solution containing Ni2+ and H+ in such concentrations that their activities equal 1. Makes sense as it is a standard state used as a reference point.

Something is wrong here, but it is hard to judge without a context. I would expect NiS(s) as a product, not mixture of elements.
 

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