Why is activity of solvated components equal to 1?

  • #1
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Homework Statement


Consider the following reaction

$$\mathrm{Ni^{2+}_{(aq)} + H_2S_{(g)} \to Ni_{(s)} + S_{(s)} + 2H^{+}_{(aq)}}$$

What are the activities of the terms in the reaction?

Homework Equations



The activity is defined as ##a = c/c^\circ## in ##\mathrm{ mol \, dm^3}##

3. The Attempt at a Solution


I do not understand why textbook gives ##a_\mathrm{Ni^{2+} (aq)} =1## and ##a_\mathrm{2H^{+} (aq)} =1##: how can I say that those activities are ##1##? Is there a rule to understand activites of solvated compontents (aq)?
 

Answers and Replies

  • #2
It is not always possible, but you can rather easily prepare a solution containing Ni2+ and H+ in such concentrations that their activities equal 1. Makes sense as it is a standard state used as a reference point.

Something is wrong here, but it is hard to judge without a context. I would expect NiS(s) as a product, not mixture of elements.
 

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