The reactivity of elements in a group or row on the Periodic Table of Elements (PTOE) is determined by their electron configuration and atomic structure. In general, as you move down a group on the PTOE, the reactivity of elements tends to increase due to the addition of more electron shells and a larger atomic radius. However, there are exceptions to this trend.
In the case of F and n in row 2, F is more reactive than n because it has a smaller atomic radius and a higher electronegativity. This means that F has a stronger ability to attract and gain electrons, making it highly reactive in chemical reactions. On the other hand, n has a larger atomic radius and lower electronegativity, making it less reactive.
For Li and Rb in row 2 and 5 respectively, the trend of increasing reactivity as you go down the group does not apply. This is because Li has a unique electron configuration with one valence electron, making it highly reactive in certain situations. Rb, on the other hand, has a full outer electron shell, making it less reactive compared to Li.
It is important to note that the reactivity of elements is also affected by other factors such as the presence of other elements in a compound and external conditions like temperature and pressure. Therefore, while the general trend of increasing reactivity as you go down a group on the PTOE holds true, there are exceptions that can be explained by the specific electron configurations and properties of each element.