Why is H2SO4 used in the contact process for sulfuric acid production?

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Discussion Overview

The discussion revolves around the use of sulfuric acid (H2SO4) in the contact process for sulfuric acid production. Participants explore the role of H2SO4 as both a solvent and a reactant, questioning the rationale behind its use in a process that ultimately produces more of the same acid. The conversation includes technical aspects of the process, such as the recycling of H2SO4 and the impact of impurities on catalyst efficiency.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant questions the necessity of using H2SO4 in the contact process if it is also produced by that method.
  • Another participant suggests that H2SO4 acts as a solvent and can be recycled, leading to a net production of H2SO4.
  • A participant inquires about the effect of impurities in SO2 and O2 on the efficiency of the V2O5 catalyst.
  • It is noted that impurities can adsorb on the catalyst, hindering the reaction at the surface.
  • Concerns are raised about the recycling of H2SO4 when used as a spray in the process.
  • One participant explains that H2SO4 is used to dissolve SO3, yielding oleum, which is then diluted to form H2SO4 again.
  • Another participant emphasizes that the process yields more H2SO4 than is initially used.
  • It is mentioned that not all H2SO4 is recycled, but a significant amount remains in the final product.
  • Participants discuss the efficiency of H2SO4 when used as a spray, suggesting it consumes less acid compared to the yield of the final product.

Areas of Agreement / Disagreement

Participants express differing views on the efficiency and necessity of using H2SO4 in the contact process, with some asserting its role as a solvent and others questioning the net advantage of its use. The discussion remains unresolved regarding the overall benefits and implications of H2SO4's dual role in the process.

Contextual Notes

Participants reference various sources for information, indicating a search for deeper understanding. There are unresolved questions about the specifics of H2SO4's recycling and its efficiency in different roles within the process.

gracy
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I have a doubt please look at this video
At time 1:54 to 2:00 and from time 3:24 to 3:29 After looking at video at time i have mentioned ,one will find that H2SO4 is itself used in this process so my question is what's the point in making H2SO4 by this method,as the method itself requires H2SO4.What's the net advantage when we are using H2SO4 (along with many other chemical compounds such as SO2,V2O5)and then producing the same?
 
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If I remember correctly, H2SO4 is used as a solvent. There is a net production of H2SO4 in that process as the acid serving as solvent can be recycled.
 
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DrDu said:
If I remember correctly, H2SO4 is used as a solvent. There is a net production of H2SO4 in that process as the acid serving as solvent can be recycled.
OK one more question how impurities in SO2 and o2 reduces the efficiency of V2O5 (used as catalyst) in this process?
 
They get adsorbed on the catalys thus hindering the reactants to react at the surface.
 
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DrDu said:
They
they means impurities ,right?
DrDu said:
at the surface.
at the surface of catalyst V2O5 ,right?
 
Yes, yes
 
DrDu said:
If I remember correctly, H2SO4 is used as a solvent. There is a net production of H2SO4 in that process as the acid serving as solvent can be recycled.
OK this explains only about when H2SO4 is used as a solvent but what about when H2SO4 is used as spray?look at this in the video At time 1:54 to 2:00 .how can this be recycled?
 
There are tons of information readily available on the net. Which ones did you check besides this video?
 
  • #10
DrDu said:
There are tons of information readily available on the net. Which ones did you check besides this video?
So i have searched a lot but such type of in depth questions (as my post 7)can only be answered here.That's why i request you to answer my post 7.
Regards.
 
  • #11
The sulfuric acid is used to dissolve the SO3 formed which yields oleum. The latter is diluted to form H2SO4 again. So where is the problem?
 
  • #12
DrDu said:
The sulfuric acid is used to dissolve the SO3 formed which yields oleum. The latter is diluted to form H2SO4 again. So where is the problem?
That's what the problem is,We are using H2SO4 to produce H2SO4 what's the net advantage?
 
  • #13
That you get more H2SO4 than you put in.
 
  • #14
According to your post 2 that H2SO4 is recycled again,right?
 
  • #15
Yes, but obviously not all of it.
 
  • #16
DrDu said:
Yes, but obviously not all of it.
And H2SO4 when used as spray consume very less amount of H2SO4 as compared to high yield of end product H2SO4,right?
 
  • #17
Acid used in the process is not consumed, it is still present in the final product.
 

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