Why is mercury a liquid even though its atoms are closely packed

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SUMMARY

Mercury remains a liquid at room temperature due to the strong bonding of its outer electrons, which prevents them from forming solid structures despite the high density of the metal. The unique properties of mercury arise from its atomic structure, where the outer valence electrons are tightly bound to the nucleus, inhibiting the formation of a solid lattice. This contrasts with substances like ice, which has a lower density due to its hexagonal lattice structure. The discussion highlights the importance of atomic bonding and crystal structure in determining the state of matter.

PREREQUISITES
  • Understanding of atomic structure and electron configuration
  • Knowledge of chemical bonding, particularly metallic bonding
  • Familiarity with crystal lattice structures
  • Basic principles of density and state of matter
NEXT STEPS
  • Research the properties of metallic bonding in elements like mercury and gold
  • Explore the concept of crystal lattice structures and their impact on density
  • Study the anomalies of water and ice density compared to other substances
  • Investigate the behavior of noble gases and their electron configurations
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Chemists, materials scientists, and students studying physical chemistry or materials science will benefit from this discussion, particularly those interested in the properties of metals and the factors influencing states of matter.

jablonsky27
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the density of ice(solid) is less than that of water(liquid) and density of mercury(liquid) is more than that of many solids.
thinking about it, it seemed natural to me that the more closely are the atoms or molecules packed the greater will be their density. but on packing them closely, isn't the state also going to be more solid-like?
so what determines a substances density and what determines its state?
what keeps the H20 molecules in place in ice but not as tightly packed as in liquid water so that its density is reduced? and why is mercury a liquid even though its atoms are (obviously?) closely packed?
 
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Water is anomalous in it's solid state being less dense than liquid.
It depends on the crystal structure which depends on the bond angle and chemical nature of the bonds.

Mercury is a liquid because it's outer electrons are very strongly bonded.
Strongly attatched outer electrons aren't free to bond with other atoms and so the metal is softer because it takes less energy to break the bonds. Mercury is the ultimate example of this.
Gold has a half full outer shell and so also has relatively weak bonds to other atoms and is a soft metal.
 
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Ya, as was mentioned, water ice is an anomaly and the reason is because it forms a hexagonal lattice structure like the one shown here:

http://www.cs.cmu.edu/~dst/ATG/images/ice1h.gif

Therefore, if you look at the lattice structure you'll see that there is a lot of open space and thus it has a lower density. However, it is not the general case that a molecule will form such an open spacious lattice
 
thanks mgb_phys and maverick_starstrider. i understand that water-ice is an anomaly.

Mercury is a liquid because it's outer electrons are very strongly bonded.
Strongly attatched outer electrons aren't free to bond with other atoms and so the metal is softer because it takes less energy to break the bonds. Mercury is the ultimate example of this.
Gold has a half full outer shell and so also has relatively weak bonds to other atoms and is a soft metal.

What are the outer electrons in mercury strongly bonded to? Do you mean that outer electrons(valence electrons right?) are not easily available to participate in reactions? In mercury, which is a metal, the outer electrons are 'free' in a sense to conduct electricity right?

Is that also why all the 'stable' elements like He, Ne, Ar etc are gases?
 
The outer electrons - like all the others are strongly attracted to the nucleus, in mercury the large mass and charge of the nucleus mean the outer valence electrons are very strongly held - so aren't available to do the nomal free electron sea metal thing. (although they must have some freedom or mercury wouldn't be shiny!)

http://antoine.frostburg.edu/chem/senese/101/periodic/faq/why-is-mercury-liquid.shtml

The noble gases are gases because theie outer shells are completely full and so there are no free electrons to bond with other atoms of the same species. If the atoms are all on their own they are pretty much forced to be a gas. Interestingly mercury gas is single atoms like a noble gas.
 

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