Why Is MgF2 the Hardest Among NaF, NaI, MgI2, and CaI2?

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SUMMARY

The discussion centers on the hardness comparison among NaF, NaI, MgF2, MgI2, and CaI2, concluding that MgF2 exhibits the greatest hardness. The hardness is influenced by the strength of ionic bonds, which are determined by Coulombic forces, specifically the charges of the ions and the distances between them. Participants suggest focusing on the ionic radii and charge density of the ions to understand the underlying reasons for MgF2's superior hardness.

PREREQUISITES
  • Understanding of ionic bonding and Coulomb's law
  • Familiarity with ionic radii and charge density concepts
  • Basic knowledge of material hardness measurement techniques
  • Experience with comparative analysis of chemical compounds
NEXT STEPS
  • Research the relationship between ionic charge and hardness in ionic compounds
  • Study the concept of charge density and its effect on material properties
  • Explore experimental methods for measuring hardness, such as Mohs scale
  • Investigate the role of ionic radii in determining the stability of ionic compounds
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Chemistry students, materials scientists, and researchers interested in the properties of ionic compounds and their applications in various fields.

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Homework Statement


Which of the following is expected to have the greatest hardness?
NaF
NaI
MgF2
MgI2
CaI2

The Attempt at a Solution


I can not seem to find what affects the hardness of them, only how to calculate it after you have the data from experiments via google. I know the answer is MgF2 I do not know how though :/. Any help as to what direction to look would be tremendously helpful.
 
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Think in terms of coulomb forces - charges and distances.
 

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