Why is Potassium Nitride (K3N) unstable?

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Discussion Overview

The discussion revolves around the stability of Potassium Nitride (K3N) and its comparison with other potassium-nitrogen compounds such as KN and K2N. Participants explore the conditions under which these compounds might be stable or unstable, as well as the implications of combining potassium and nitrogen.

Discussion Character

  • Exploratory, Technical explanation, Conceptual clarification

Main Points Raised

  • One participant questions the stability of K3N and asks if KN and K2N are similarly unstable.
  • Another participant suggests that the question of stability should focus on which combinations of atoms can be stable rather than why K3N is unstable, emphasizing the role of energy in determining stability.
  • A participant mentions the importance of comparing the energy gain from forming K-N bonds with the dissociation energy of N2 to assess stability.
  • One participant expresses interest in creating a compound similar to potassium amide and indicates a desire to clarify their goals in a separate question.
  • A link to additional information about potassium nitride is provided for further context.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the stability of K3N or the other potassium-nitrogen compounds. Multiple viewpoints regarding the nature of stability and the factors influencing it are presented.

Contextual Notes

The discussion does not resolve the assumptions regarding energy comparisons or the specific conditions under which potassium and nitrogen might react.

ProjectFringe
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Hi, can anyone tell me why Potassium Nitride (K3N) is unstable? Also are KN and K2N, electrons aside, just as unstable?

If so, what happens when potassium and nitrogen are combined? No reaction?

Thanks!:biggrin:
 
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It is a bit putting things on a head. There are countless combinations of atoms that are unstable, so the real question is not "why it is unstable?", but "which combinations have a chance of being stable?".

But in general question about stability is one of the energy: does the new combination have lower energy than its composing parts? In this particular case: is the energy gain due to the creation of three K-N bonds higher, than the dissociation energy of N2?
 
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Thanks for your response! I'm trying to figure out how to make a compound similar to potassium amide, but I think it will be easier for me if I just explain what I'm trying to make and then see if it is possible. I'll try posting it as a different question. Thanks again :biggrin:
 

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