Mandragonia
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Jilang said:I find this really fascinating. The Schroedinger Equation is a diffusion equation with an imaginary diffusion coefficient (or real diffusion in imaginary time?) Is that just a coincidence or is there some underlying process driving it? Why would it become more uncertain over time?
1. Is it just coincidence?
Yes, I think so. The main focus of Erwin Schroedinger and his colleagues was on building a model that describes the atomic structure and its properties, in particular emission and absorption spectra. The behaviour of free electrons was (presumably) less important.
2. Is there some underlying process driving it?
The spreading of a wave packet is regarded a consequence of Heisenberg's uncertainty principle.
3. Why would it become more uncertain over time?
A free electron can be in sharply localized state at t=0, with small uncertainty in position dx and some uncertainty in velocity dv. If you wait for some time, the wave packet evolves. The uncertainty in position increases due to the additional uncertainty in the velocity. Finally it becomes of the order t*dv, which can be much larger than the initial uncertainty dx.