Why is the de Broglie wavelength larger than the particle it represents?

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Discussion Overview

The discussion revolves around the concept of the de Broglie wavelength and its relationship to the size of particles it represents. Participants explore the implications of quantum mechanics, the nature of particle size, and the conditions under which the de Broglie wavelength may exceed the physical dimensions of particles. The scope includes theoretical interpretations and conceptual clarifications.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants assert that the de Broglie wavelength is a prediction of quantum mechanics that does not necessarily correlate with the physical size of particles, particularly for elementary particles like electrons and neutrinos.
  • It is suggested that for large molecules or atoms with low momentum, the de Broglie wavelength can exceed the size of the particle.
  • A question is raised about whether the size of a particle should be considered as the de Broglie wavelength or if only part of the wavelength exists within the particle's diameter.
  • One participant discusses the use of X diffraction to evaluate particle size, indicating that the definition of "size" may vary based on experimental context.
  • Another participant mentions the need for clarity regarding the term "size of a particle," questioning the assumption that particles can be treated as corpuscles.
  • There is a correction regarding terminology, where "Compton diffusion" is clarified to mean "Compton scattering," highlighting potential language barriers in scientific discussions.

Areas of Agreement / Disagreement

Participants express differing views on the relationship between de Broglie wavelength and particle size, with no consensus reached on the definitions or implications of particle size in relation to quantum mechanics.

Contextual Notes

Participants note that the concept of particle size may depend on experimental conditions and definitions, and there are unresolved questions regarding the implications of the de Broglie wavelength in various contexts.

jaketodd
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Why is the de Broglie wavelength sometimes larger than the particle it describes?

Thanks,

Jake
 
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jaketodd said:
Why is the de Broglie wavelength sometimes larger than the particle it describes?

Thanks,

Jake

Because that's what QM (the most successful physical theory to date) predicts, and those predictions agree with experiments.

Also for some particles (i.e. electrons & neutrinos), there is no known "size" that can be associated with the particles themselves, so if the de Broglie wavelength is measurable, then it is automatically "larger" than the particles.
 
If you have cold (i.e. little momentum) big molecules/ atoms, than for example Broglie wave length will exceed the size of the particle.
 
Should the particle size be the de Broglie wavelength, or does only part of the wavelength exist at a time (what can fit inside the particle's diameter)?
 
Jaketodd, There were two points made in the responses above that bear repeating. One, that the de Broglie wavelength h/p is not related in any way to the size of the particle. Only to its momentum, and is a measure of how localized its wavefunction is. Two, that all elementary particles including electrons, quarks, etc are, to our best knowledge, point particles.
 
So is a particle's wavefunction size/localization the size of the de Broglie wavelength?

Thanks,

Jake
 
Please let us know what a "size of a particle" could be.
Radiocrystallographists use the width of X diffraction rays to evaluate the size of the diffracting crystallites. So clays give broad diffration peaks on a Debye-Scherrer diffractograms, though silts give fine peaks. I could confuse in justice an international crook by such facts. To give precise spots or peaks, the Bragg law demands large crystallites, and monochromatic waves, so with long and broad spindle of each incident quanton, photon or neutron or electron.

For instance, we obtained broad spots by diffracting electrons on a carbide inclusion in a Laue diffractogram, in a Siemens electronic microscope. The monochromaticicty of the electrons was not so perfect, and maybe the carbide inclusion was not a so perfect crystal.

When you write or say "size of a particle", you surrepticiously mean that it is or can be a corpuscle. But where are the experiments that could support such a postulate ?

A little more has to be known : the broglian period, frequency and when moving the broglian wavelength, suffice when an electron interferes with itself - in an Aharanov-Bohm experiment, for instance.
But when an electron interferes whith electromagnetic fields, a photon for instance in a Compton scattering, then the intervening period is the Dirac-Schrödinger, [itex]\frac{h}{2mc^2}[/itex], half of the broglian one. So is the wavelength, too.
 
Last edited:
Jacques_L said:
Please let us know what a "size of a particle" could be.
Radiocrystallographists use the width of X diffraction rays to evaluate the size of the diffracting crystallites. So clays give broad diffration peaks on a Debye-Scherrer diffractograms, though silts give fine peaks. I could confuse in justice an international crook by such facts. To give precise spots or peaks, the Bragg law demands large crystallites, and monochromatic waves, so with long and broad spindle of each incident quanton, photon or neutron or electron.

For instance, we obtained broad spots by diffracting electrons on a carbide inclusion in a Laue diffractogram, in a Siemens electronic microscope. The monochromaticicty of the electrons was not so perfect, and maybe the carbide inclusion was not a so perfect crystal.

When you write or say "size of a particle", you surrepticiously mean that it is or can be a corpuscle. But where are the experiments that could support such a postulate ?

A little more has to be known : the broglian period, frequency and when moving the broglian wavelength, suffice when an electron interferes with itself - in an Aharanov-Bohm experiment, for instance.
But when an electron interferes whith electromagnetic fields, a photon for instance in a Compton diffusion, then the intervening period is the Dirac-Schrödinger, [itex]\frac{h}{2mc^2}[/itex], half of the broglian one. So is the wavelength, too.

This is the second time you have mentioned "Compton diffusion" ... the context seems to suggest you mean "Compton scattering" .. is that correct? I think in French, the word for scattering might be "diffusion", however in English, diffusion has a different meaning in the context of physics.
 
SpectraCat said:
This is the second time you have mentioned "Compton diffusion" ... the context seems to suggest you mean "Compton scattering" .. is that correct? I think in French, the word for scattering might be "diffusion", however in English, diffusion has a different meaning in the context of physics.

Thank you for correcting my english. You are right.
 
  • #10
Jacques_L said:
Thank you for correcting my english. You are right.

No problem .. I didn't think there was any such thing as "Compton diffusion", but I wasn't completely sure, so I figured I check.

Also, I should have done this before: Welcome to PF!
 
  • #11
SpectraCat said:
Also, I should have done this before: Welcome to PF!
Thanks for the welcome.
It is a pleasure to exchange in a so cooperative spirit.

I came here because of a cross reference to the thread initiated by Ruth Kastner.
I am among those who rediscovered independently the TIQM, but I came far later than John G. Cramer. Anyway I was the first to give a first approximation of the diameter of Fermat's spindle between emitter and absorber. An approximation which could be much more rigourous.

I think in french, then translate, and the results may be so-so... My english has rusted, in the meantime.
 

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