Why is the Raman spectrum for iron oxide not showing a signal?

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    Iron Raman Spectrum
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Discussion Overview

The discussion revolves around the lack of a Raman signal when testing iron oxide, specifically focusing on the participant's experiences with a new Raman spectrometer and the challenges encountered in obtaining results from iron oxide samples.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant reports successful Raman spectroscopy results with liquids and other solid samples but receives no signal from iron oxide.
  • Some participants question whether iron oxide is Raman active, suggesting that if it is not, no signal would be expected.
  • Another participant mentions that iron oxide, specifically Goethite, is known to have Raman features, including a strong peak at 390 cm-1.
  • The original poster confirms testing of other solid samples, such as graphite and amorphous carbon, which yielded correct signals, but still no signal for iron oxide.

Areas of Agreement / Disagreement

Participants express uncertainty regarding the Raman activity of iron oxide, with some asserting it should have detectable features while others remain skeptical. The discussion does not reach a consensus on the reasons for the lack of signal.

Contextual Notes

There are unresolved questions about the Raman activity of different forms of iron oxide and the specific conditions under which the spectrometer was used. The discussion also highlights the importance of testing known samples to validate the spectrometer's functionality.

Who May Find This Useful

Researchers and practitioners in materials science, chemistry, and spectroscopy, particularly those interested in Raman spectroscopy and its applications to metal corrosion and oxide materials.

amayas
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RAMAN spectrum of iron oxide !

Dear every one!

I have just got a new raman spectrometer to study the corosion of metals.
i tested it on liquids (alcool, benzene, solvant ...) it works very well.
i did also experiments on coal and carbon, perfect !

but when i tested on iron oxide .. i got no signal at all!

please, does anyone know what may be wrong?

thanks a thousand

amayas
 
Last edited:
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I am not sure if iron oxide is Raman active. If it isn't, it won't show the effect.
 
Have you tested it on non-liquid samples, for example something with well a known Raman peak like a piece of a silicon wafer or something?
 
Dr Transport said:
I am not sure if iron oxide is Raman active. If it isn't, it won't show the effect.

Hi every one !

thank you for your anwers, Yes, Iron oxide has well known features in Raman.
i am using Goethite , it has a strong feature at 390 cm-1.

... still trying ...

thansk again
 
JustinLevy said:
Have you tested it on non-liquid samples, for example something with well a known Raman peak like a piece of a silicon wafer or something?


Dear Levy Justin,

Yes, I have tested the graphite and amorphous carbon.

I git the correct signal (with some additional strong pics , ... that i getevery time i study solid samples!)

but no signal for my iron oxide

thanks again

amayas
 

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