Why is the use of tert-butyl methyl ether favoured over using diethyl ether?

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SUMMARY

The use of tert-butyl methyl ether (TBME) is favored over diethyl ether due to its steric hindrance, which reduces the likelihood of unwanted side reactions during chemical processes. TBME's bulkiness provides better solvation properties for compounds like trans-stilbene, enhancing purification efficiency. Additionally, TBME's lower volatility compared to diethyl ether minimizes evaporation losses and improves safety in laboratory environments.

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Homework Statement


Why is the use of tert-butyl methyl ether favoured over using diethyl ether?

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The Attempt at a Solution


After the formation of trans-stilbene, tert-butyl methyl ether was used to dissolve trans-stilbene. Water was added to dissolve any impurities which was absorbed by calcium chloride pellets along with the impurities. I guess the reason why tert-butyl ether was used is due to the bulkiness of the substituents in comparison to diethyl ether, but I don't know what that would do in comparison. Why was tert-butyl ether used as opposed to diethyl ether? It is not due to safety or cost concerns is what I do know. However, I don't know what the answer is or how to find it. Please help. Much appreciated. :)
 
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