I still don't understand your problem.
Let's take the simplest case of a nondegenerate discrete spectrum. Then the operator ##\hat{A}## representing the observable ##A## has a complete set of orthonormal vectors ##|a \rangle##, i.e., each eigenspace is onedimensional. Now let the system be prepared in a pure state, represented by a unit ray in Hilbert space and let ##|\psi \rangle## be a representant of this ray. Then the probability to find the value ##a## when measuring the observable ##A## is
$$P(a|\psi)=|\langle a|\psi \rangle|.$$
These are non-negative real numbers. Since the vector ##|\psi \rangle## by definition is normalized and since the orthonormal set ##|a \rangle## is complete, you have
$$1=\langle \psi |\psi \rangle=\sum_a \langle \psi|a \rangle \langle a|\psi \rangle=\sum_a |\langle a|\psi \rangle|^2=\sum_a P(a|\psi),$$
i.e., ##P(a|\psi)## are indeed a correct set of probabilities for the outcome of measurements of observable ##A## provided the system is prepared in the said pure state.