Work per particle of a NaCl chain

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SUMMARY

The discussion focuses on calculating the work per particle in an infinite NaCl chain, specifically addressing the interaction energies between ions. The key formula involves the sum of interaction energies, represented as ##U(0,1) + U(-1,0) + U(0,2) + U(-2,0) + \dots##, which leads to the total energy per particle being proportional to ##\sum\limits_{\substack{m,n \\ m PREREQUISITES

  • Understanding of ionic interactions and potential energy in solid-state physics.
  • Familiarity with series expansions, particularly the series expansion of ##ln(2)##.
  • Knowledge of electrostatic principles, specifically Coulomb's law and its applications.
  • Basic skills in mathematical summation and manipulation of infinite series.
NEXT STEPS
  • Study the derivation and implications of Coulomb's law in ionic compounds.
  • Learn about series expansions and their applications in physics, focusing on logarithmic functions.
  • Explore the concept of energy per particle in infinite systems, particularly in solid-state physics.
  • Investigate methods to avoid double counting in summation problems involving infinite series.
USEFUL FOR

Students and researchers in solid-state physics, chemists studying ionic compounds, and anyone interested in the thermodynamic properties of materials.

guyvsdcsniper
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Homework Statement
Find the work per particle required to assemble such a configuration.
Problem
Relevant Equations
W=qV
The problem states to find the work per particle to assemble the following NaCl chain.
I just want to post my work here to verify I have the correct answer.

My work is attached in the image provided.
Screen Shot 2022-02-28 at 5.02.37 PM.png
 
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Is this chain supposed to be infinite? (or of length 8?)
 
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ergospherical said:
Is this chain supposed to be infinite? (or of length 8?)
Ah it does say infinite, I missed that in the question.
 
Right. Well in that case, focus on a particular ion in the chain (labelled "0" below):
##\dots \ominus_{-3} \oplus_{-2} \ominus_{-1} \oplus_0 \ominus_1 \oplus_{2} \ominus_{3} \dots##

Let the interaction energy between ##m## and ##n## be ##U(m,n)##. Assuming each ion to be separated by a distance ##a## from its nearest neighbours, what's the sum of the interaction energies of all the pairs including the ion ##n=0##, i.e. ##U(0,1) + U(-1,0) + U(0,2) + U(-2,0) + \dots##?

How might you use this to work out the total energy per particle, which is proportional to ##\sum\limits_{\substack{m,n \\ m<n}} U(m,n)##? Be careful not to double count.
 
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Edited

If you haven't already sorted this out, here are a couple of hints which should help:
- familiarise yourself with the series expansion of ##ln(2)##;
- make your working simpler/neater by defining ##A = \frac {q^2}{4 \pi \epsilon_0}##.
 
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I figured it out. Thank you both for your help.
 
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