Work per particle of a NaCl chain

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Homework Help Overview

The problem involves calculating the work per particle required to assemble an infinite chain of NaCl. Participants are discussing the implications of the chain's length and the interaction energies between ions.

Discussion Character

  • Exploratory, Assumption checking, Conceptual clarification

Approaches and Questions Raised

  • Participants are questioning whether the chain is infinite or of a specific length. One participant suggests focusing on a particular ion and calculating the sum of interaction energies with its neighbors. Hints regarding series expansions and simplifications are also provided.

Discussion Status

The discussion is ongoing, with participants exploring different interpretations of the problem. Some guidance has been offered, including hints about mathematical concepts and simplifications, but there is no explicit consensus on the approach yet.

Contextual Notes

There is a mention of potential confusion regarding the chain's length and the need to avoid double counting in the calculation of interaction energies.

guyvsdcsniper
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Homework Statement
Find the work per particle required to assemble such a configuration.
Problem
Relevant Equations
W=qV
The problem states to find the work per particle to assemble the following NaCl chain.
I just want to post my work here to verify I have the correct answer.

My work is attached in the image provided.
Screen Shot 2022-02-28 at 5.02.37 PM.png
 
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Is this chain supposed to be infinite? (or of length 8?)
 
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ergospherical said:
Is this chain supposed to be infinite? (or of length 8?)
Ah it does say infinite, I missed that in the question.
 
Right. Well in that case, focus on a particular ion in the chain (labelled "0" below):
##\dots \ominus_{-3} \oplus_{-2} \ominus_{-1} \oplus_0 \ominus_1 \oplus_{2} \ominus_{3} \dots##

Let the interaction energy between ##m## and ##n## be ##U(m,n)##. Assuming each ion to be separated by a distance ##a## from its nearest neighbours, what's the sum of the interaction energies of all the pairs including the ion ##n=0##, i.e. ##U(0,1) + U(-1,0) + U(0,2) + U(-2,0) + \dots##?

How might you use this to work out the total energy per particle, which is proportional to ##\sum\limits_{\substack{m,n \\ m<n}} U(m,n)##? Be careful not to double count.
 
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Edited

If you haven't already sorted this out, here are a couple of hints which should help:
- familiarise yourself with the series expansion of ##ln(2)##;
- make your working simpler/neater by defining ##A = \frac {q^2}{4 \pi \epsilon_0}##.
 
Last edited:
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I figured it out. Thank you both for your help.
 
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