You aren't getting a string of calculations, it's telling you the exact values of the 4 roots. If all you need are approximations, try N[Solve[LaguerreL[4, 2, x] == 0, x]]. That will give you a list of the approximate values of the 4 roots. If you need more precision in the answer you can use N[Solve[LaguerreL[4, 2, x] == 0, x],6] to get the answer to six decimal places. Be warned, though, depending on what algorithms Mathematica has to use to get the solutions you may not be able to get six decimal precision.
-Dan