The zeroth component of the spin 4-vector is zero in the rest frame of a particle because it represents the spatial direction of the particle's spin axis, which must be orthogonal to the particle's 4-velocity. In this frame, the 4-velocity is (1, 0, 0, 0), enforcing that the zeroth component of the spin 4-vector must also be zero. The spin 4-vector can be viewed as the expectation value of the quantum mechanical spin or as the spin of a gyroscope, defined along the world-line of the particle. This framework allows for the definition of a 2-form that quantifies angular momentum about an instantaneous axis in the center of mass frame. The discussion emphasizes the conceptual and mathematical foundations of the spin 4-vector in relativistic contexts.