hokhani
- 647
- 28
- TL;DR
- Classical model confines the particle while quantum mechanics doesn't.
Take as an example the quantum state ##\gamma_{3,3}## of angular momentum where ##\vec{L}## makes the angle ##\frac{\pi}{6}## with ##z-## axis. This angular momentum state in classical model, describes a circular motion in a plane perpendicular to ##\vec{L}##. So, in all the possible motions, the particle cannot have polar angle less than ##\frac{\pi}{3}##. However, in quantum model this motion is described by ##\gamma_{3,3}\propto \sin^3{\theta}##, i.e., the particle can be present in every polar angle except for zero. It's weird that we have the angular momentum operator as ##\hat{L}=\hat{r} \times \hat{p}## which is like classical model (except for replacing the operators with quantities) but the two models seem not compatible.