Final Volume of Ideal Gas After Equilibrium

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SUMMARY

The discussion focuses on determining the final volume of two ideal gases (n moles of gas A and m moles of gas B) in an adiabatic system after reaching equilibrium. The ideal gas law is applied, leading to the equations \(\frac{P_AV_A}{T} = nR\) and \(\frac{P_BV_B}{T} = mR\). At equilibrium, the pressures equalize, allowing for the derivation of the final volumes \(V_A\) and \(V_B\). A mathematical error was identified in the initial setup, emphasizing the importance of accurate calculations in thermodynamic problems.

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  • Understanding of the Ideal Gas Law
  • Knowledge of thermodynamic principles, specifically adiabatic processes
  • Familiarity with equilibrium concepts in physical chemistry
  • Basic algebra for solving equations
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Homework Statement


Two ideal gas (n mole A and m mole B) was separated by a piston (impermeable and diathermal) the whole setup is confine in a adiabatic walls so no heat exchange with outside. Let the piston move, at equilibrium, find the final volume. Assume the final temperature of both gas is T and the total volume is V.

2. The attempt at a solution
First of all, both gas satisfy ideal gas state equation

<br /> \frac{P_AV_A}{T_A} = nR, \qquad \qquad \frac{P_BV_B}{T_B} = mR<br />

Since we know the final temperature, and at equilibrium, the pressure is the same on both compartment (otherwise, the piston will move), so assuming the final volume of A is V_A, then the final volume of B will be V-V_B, we conclude that

<br /> \frac{P}{T} = nRV_A = \frac{P}{T} = mR(V-V_A)<br />

We can solve for V_A and V_B, right?
 
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Your setup looks correct, except for a mathematical error...
If \frac{P V}{T} = n R, then \frac{P}{T} = \cdots ?

By the way, once you have found the answer, it'll be nice trying to explain its physical meaning and saying something about whether you could have foreseen the outcome.
 
CompuChip said:
Your setup looks correct, except for a mathematical error...
If \frac{P V}{T} = n R, then \frac{P}{T} = \cdots ?

By the way, once you have found the answer, it'll be nice trying to explain its physical meaning and saying something about whether you could have foreseen the outcome.

Oh, careless. Thanks
 

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