1st order, 2nd order Rate reactions HELP

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SUMMARY

This discussion clarifies the concepts of first order, second order, and zero order rate reactions in chemical kinetics. A first order reaction has a rate that is directly proportional to the concentration of one reactant, while a second order reaction can either depend on the square of one reactant's concentration or the product of two reactants' concentrations. The overall order of a reaction is the sum of the individual orders, as demonstrated with the example of the reaction A + B → C, where the differential rate law is expressed as rate = k[A][B]^2, resulting in an overall order of 3.

PREREQUISITES
  • Understanding of chemical kinetics
  • Familiarity with differential rate laws
  • Knowledge of molarity and concentration
  • Basic algebra for interpreting reaction rates
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  • Study the derivation of the integrated rate laws for first and second order reactions
  • Learn about the method of initial rates for determining reaction orders
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brandon1
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1st order, 2nd order Rate reactions HELP!

I have read the section of my book over and over and studied the practice problems, but I still do not understand 1st order, 2nd order, or 0 order rate reactions. What does it mean to be of any particular order?
 
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what are you talking about?

what lesson are you reading?

you information is incomplete, I'm sorry... that's why i cannot understand the order that you're referring to...
 
the order is just the relationship between the molarity of a reactant and the amount that it affects the rate of the reaction.
 
oh! so that's what brandon meant... lol! i didn't get it first...
 
If the rate of a reaction is given by :

rate= dP/dt = k*[A]^a \cdot <b>^b \cdot [C]^c \dots </b>

then the order of the reaction is said to be a+b+c+...

So, a first order reaction has a rate that is linearly proportional to the concentration of one of the reactants. A second order reaction can be one of the two following kinds :

rate = k*[A]^2
or
rate = k*[A]

A zero order reaction has a rate that is independent of the concentration of any of the reactants.
 
Let's say you have the following data:

A + B ---> C

[A]-----------reaction rate
.010----.020-----.050
.020----.020-----.100
.020----.040-----.400

Look at the first and second lines; [A] increases by a factor of 2 as does the reaction rate ( is held constant). 2^x = 2? x = 1, so [A] is a first order reactant. Now look at lines 2 and 3; [A] is held constant, increases by a factor of 2, and the reaction rate increases by a factor of 4. 2^x = 4? x = 2, so is a second order reactant.

Now you right the differential rate law like this: rate = k[A]^2. The overall order of the reaction is 3.
 

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