2 ways to calculate net standard reduction potential

In summary, on chemwiki, there are 2 equations provided to find the standard reduction potential of a cell: Eocell = Eocathode + Eoanode and Eocell = Eocathode - Eoanode. These equations are used to determine the overall cell potential and the absolute potential, respectively. The first equation follows the American convention, while the second one follows the European convention. However, it is important to note that the sign of the overall cell potential can be a matter of convention, but the absolute potential should not be. It is possible that there is a mistake in these formulas, as the sign may have been omitted in one of them. Additionally, calculating the spontaneity of a reaction
  • #1
TT0
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On chemwiki, they gave 2 equations to find the standard reduction potential of a cell:

Eocell = Eocathode + Eoanode

Eocell = Eocathode - Eoanode

Why are there 2 equations and when do you use each one?

Thanks
 
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  • #2
European convention and American convention and before you ask, "No, I can no longer tell you the differences, nor which is to be preferred."
 
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  • #3
Is the first one the American convention? (Im taking the SAT)
 
  • #4
Unless I am missing something I feel like there is a mistake in these formulas. Sign of the overall cell potential can be a matter of convention, but the absolute potential shouldn't be. I wonder if they did not omit a minus sign in one of the formulas.
 
  • #5
Would calculating spontaneity of reaction be the 2 reduction potentials just added to each other?
 

1. What is net standard reduction potential?

Net standard reduction potential is a measure of the tendency of a chemical species to gain electrons and undergo reduction reactions. It is a standardized value that represents the potential energy difference between a reduction reaction and a standard hydrogen electrode.

2. What are the two ways to calculate net standard reduction potential?

The two ways to calculate net standard reduction potential are through the Nernst equation and through the use of standard reduction potential tables. The Nernst equation uses the concentrations and activities of reactants and products to calculate the net standard reduction potential, while the tables provide a list of standardized reduction potentials for various reactions.

3. How is the Nernst equation used to calculate net standard reduction potential?

The Nernst equation is used to calculate net standard reduction potential by using the concentrations and activities of reactants and products in a given reaction. The equation takes into account the temperature, number of electrons transferred, and the standard reduction potential of the reactants and products to calculate the net standard reduction potential.

4. What are standard reduction potential tables?

Standard reduction potential tables are lists of standardized values that represent the potential energy difference between a reduction reaction and a standard hydrogen electrode. These tables provide a quick reference for scientists to determine the net standard reduction potential of various reactions without having to use the Nernst equation.

5. How is net standard reduction potential used in chemistry?

Net standard reduction potential is an important concept in chemistry as it is used to predict the direction and feasibility of redox reactions. It is also used to compare the reactivity of different species and determine which species is more likely to be reduced in a given reaction. Additionally, net standard reduction potential is used to calculate the cell potential in electrochemical cells and to determine the efficiency of batteries and other energy storage devices.

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