A (probably simple) quantum problem - energy eigenfunctions?

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Homework Help Overview

The discussion revolves around a quantum mechanics problem involving a particle in an infinite potential well. The original poster presents a wavefunction and seeks to express it in terms of energy eigenfunctions, indicating some confusion regarding the concept of eigenfunctions and their relation to the time-independent Schrödinger equation.

Discussion Character

  • Exploratory, Conceptual clarification, Problem interpretation

Approaches and Questions Raised

  • The original poster attempts to understand the nature of energy eigenfunctions and how to express the given wavefunction in that context. Some participants provide insights into the relationship between the Schrödinger equation and eigenvalue problems, while others emphasize the importance of boundary conditions.

Discussion Status

The discussion is ongoing, with participants offering clarifications about the eigenvalue problem and the significance of the time-independent Schrödinger equation. The original poster expresses a gradual improvement in understanding, suggesting that the conversation is contributing positively to their learning process.

Contextual Notes

There is a mention of the original poster's frustration with the lack of instruction from their lecturer, which may impact their grasp of the material. Boundary conditions for the wavefunction are also highlighted as a critical aspect of the problem.

jeebs
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Hi people,
I have this problem to do, and its only worth one mark which makes me think it must be easy, but our lecturer has not taught us very well at all, never explains anything.

Anyway, there's a particle confined in an infinite potential well within the region -L/2 < x < L/2, where the potential is zero. At a certain time it is described by the wavefunction:
psi(x) = Acos(pi.x/L) + 2Asin(2pi.x/L). [where A = sqrt(2/5L)]

I am supposed to write down psi(x) in terms of the eigenfunctions of energy.

First off, I don't really know what an eigenfunction of energy is, or is supposed to look like, so i don't know what i am supposed to be writing psi(x) in terms of. All i have really done with this question is write down the time-independent Schrödinger equation with the V(x) term missing, since the potential is zero, so i have:

-H/2m.(d^2/dx^2)psi(x) = E(psi(x)) [where H = h/2 pi]

Other than that i have just aimlessly messed around with the equation above.
Can anybody help me out? I am desperate for help with this stuff, its starting to frustrate me now.
Thank you.
 
Last edited:
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It is "just" a second order differential equation which needs to fullfil boundary conditions psi(L/2) = psi(-L/2) = 0

You should have studied second order differential equations before studying quantum mechanics.
 
malawi_glenn said:
You should have studied second order differential equations before studying quantum mechanics.
... or during.

jeebs,

That there time-independent Schroedinger equation is the eigenvalue problem. "An eigenfunction of the energy" should really say "an eigenfunction of the Hamiltonian". And so, what you have written there is that the operator, H, acts on the wave function, psi, by simply multiplying it by some value, called the energy, E. The eigenvalue problem is especially profound in quantum mechanics, more so than in any other subject, because in quantum mechanics only the normalized projective states matter, so multiplication by a constant doesn't change any physical quantity.

Anyway, the point is, the solution to the time-independent Schroedinger equation is the eigenfunction of the energy. Then, like malawi_glenn said ...
 
aah thanks for your answers... I'm getting there with this quantum mechanics business, little by little... i understand stuff a bit more every day.
 

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