The diameter of the lens is more or less irrelevant (assuming you have a separate stop that isn't the lens itself). It's the radial distance of the marginal rays (or equivalently the numerical aperture (NA)) that matters.
If you want to quantify the amount of aberration in your system, try using an iris diaphragm to vary the NA of your system. Measure how much the focal point moves when you close the iris vs when you fully open the iris. The more the focal point moves, the worse your aberration is.Yeah, sorry I was being lazy. Here you go:
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Two rays incident at angle ##\theta## on a rectangular slab of glass. When they hit the glass, they're separated by a distance of ##2h##. Slab has a thickness ##t##. Find the position of the focal point from ##\theta##, ##h##, ##t##, and ##n## (index of the slab). Expand your answer as a series for small ##\theta##. The lowest term should be cubic and it refers to 3rd order spherical aberration.
Notice that your optical design contains a range of values of ##\theta## from 0 up to your aperture stop. That means your focal point will be smeared out over a range, giving you a caustic.