ALuminum reactions with reagents

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    Aluminum Reactions
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Discussion Overview

The discussion revolves around the identification of an orange precipitate formed from the reaction between Aluminum Nitrate and Sodium Carbonate. Participants explore potential chemical reactions, the nature of the precipitate, and the conditions under which these reactions occur.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant expresses difficulty in identifying an orange precipitate from Aluminum Nitrate and Sodium Carbonate, seeking assistance.
  • Another participant questions whether the sodium carbonate used might have been sodium chromate or dichromate, suggesting that the color of the solutions prior to mixing could provide insight.
  • A participant mentions having a reaction with chromate but also obtained an orange precipitate from clear sodium carbonate and Aluminum Nitrate, speculating it could be Al2O3 but unsure how that would form.
  • Another participant notes that most aluminum precipitates are typically white, suggesting the possibility of mislabeling the solutions or making an error in the experiment.
  • One participant proposes that the reaction may involve a redox process in the presence of water, providing half and full equations for the reaction, although they express uncertainty about the occurrence of the reaction.
  • A later reply reiterates the uncertainty regarding the formation of Al2O3 and suggests that under the given conditions, Al(OH)3 (which is white) should precipitate, potentially incorporating impurities that could impart color to the precipitate.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the identity of the orange precipitate or the conditions leading to its formation. Multiple competing views and hypotheses are presented, indicating ongoing uncertainty and debate.

Contextual Notes

Participants express uncertainty about the nature of the precipitate and the reactions involved, highlighting potential mislabeling of reagents and the influence of impurities on the observed color. The discussion includes various assumptions about the chemical processes at play.

mavsqueen06
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I'm having extreme difficulty identifying some precipitates I obtained from combining a solution of Aluminum Nitrate and Sodium Carbonate. The result was an orange precipitate. I have searched high and low (complex ions, decomposition, redox, etc) but I can't figure it out. Please HELP!
 
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Are you sure the sodium carbonate wasn't really sodium chromate or dichromate? What color were the two solutions before you combined them?
 
i did have a reaction with chromate too, but i had another with clear sodium carbonate and aluminum nitrate and got an orange ppt. I was thinking it could be Al2O3? i just don't know how that could occur.
 
Most Al precipitates I can think off are white. Carbonate is one of them. IMHO if it was orange, you may have mislabelled solutions or you did some other mistake.
 
Its been awhile since I was doing redox reactions, but I'm presuming the reaction took place in the presence of water. If so the Aluminium Nitrate should undergoe a redox reaction with the water.

Half equations:
2H2O(l) -> O2(aq) + 4H+(aq) + 4e-
Al3+(aq) + 3e- -> Al(aq)

Full equation:
6H2O(l) + 4Al3+(aq) -> 2Al2O3(s) + 4H+(aq)

The Aluminium and Water react due to their electronegativity.
 
+Minkie+ said:
Its been awhile since I was doing redox reactions, but I'm presuming the reaction took place in the presence of water. If so the Aluminium Nitrate should undergoe a redox reaction with the water.

Half equations:
2H2O(l) -> O2(aq) + 4H+(aq) + 4e-
Al3+(aq) + 3e- -> Al(aq)

Full equation:
6H2O(l) + 4Al3+(aq) -> 2Al2O3(s) + 4H+(aq)

The Aluminium and Water react due to their electronegativity.

None of this happens...
 
mavsqueen06 said:
i did have a reaction with chromate too, but i had another with clear sodium carbonate and aluminum nitrate and got an orange ppt. I was thinking it could be Al2O3? i just don't know how that could occur.
In this conditions should precipitate Al(OH)3 (white) which easily include impurities; infact this precipitation it's used to purify water. A small, not initially visible amount of coloured substance (chromate, for example) easily gives a colour to the precipitate.
 

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