Angular frequency of a matter patter

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By the de Broglie relations: E = [tex]\hbar * \omega[/tex]

Is the angular frequency ([tex]\omega[/tex]) in this equation an average or is it a constant? In other words, does the angular frequency (or the wavenumber, k) for a matter particle change, for instance, in differing gravitational fields, such as we see for a photon with gravitational redshift?
 
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I can restate the question in a related way.

Assume a spin-1/2 particle is described by a probability amplitude function ([tex]\Psi[/tex]) with angular frequency ([tex]\omega[/tex]) or wavenumber (k). The probability amplitude distribution for that particle exists within a volume of space-time. Assume that within that volume of space-time, there is an electromagnetic field that varies significantly in strength over that volume. How does that varying electromagnetic field affect the wavenumber/angular frequency of the particle's probability amplitude distribution?