Atomic Number & Orbital Energy: Explained

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SUMMARY

The discussion centers on the relationship between atomic number and orbital energy, specifically how increased nuclear charge enhances the attractive force on outer shell electrons, resulting in a decrease in orbital energy. This decrease in energy is described as becoming more negative, indicating a stronger binding energy. Participants clarify that binding energy is the energy needed to separate a system into its parts, while potential energy is the stored energy based on position. Understanding these concepts is essential for grasping atomic interactions.

PREREQUISITES
  • Understanding of atomic structure and electron configuration
  • Basic knowledge of potential energy and kinetic energy
  • Familiarity with binding energy concepts
  • Introductory physics principles related to energy
NEXT STEPS
  • Study the concept of atomic structure and electron shells
  • Learn about potential energy and its applications in physics
  • Explore binding energy in the context of atomic and molecular physics
  • Investigate the relationship between nuclear charge and electron behavior
USEFUL FOR

High school students studying chemistry and physics, educators teaching atomic theory, and anyone interested in the fundamental principles of energy in atomic interactions.

kay
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My book here says that ' Despite the shielding of the outer electrons from the nucleus by the inner shell electrons, the attractive force experienced by the outer shell electrons increases with increase of nuclear charge. In other words, the energy of interaction between the nucleus and electron (that is orbital energy) decreases (that is more negative) with the increase of atomic number. '
Now i understood the first part. But whatever is said after 'in other words', i am not able to understand what is said here.
How is more attractive force synonymous to decrease of energy of interaction b/w nucleus and electron?
 
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Yes, if your potential is more attractive you binding energy will decrease. You must keep in mind that the binding energy is negative, hence it's decrease it's actually associated with the increase of its magnitude.
 
I could not get you. :|
Idk what is potential or binding energy.
PS- I'm just a student of 11th grade.
 
kay said:
Idk what is potential or binding energy.

Potential energy is the stored energy in a system by virtue of its position. For example an apple sitting on a table has energy by virtue of the fact it is above the floor. Remove the table and it falls to the floor converting the potential energy to kinetic energy.

Binding energy is the energy required to dissemble a system into its constituent parts.

It's also probably a good idea to become familiar with what energy is in a general sense:
http://physwiki.ucdavis.edu/Classic..._Mass_and_Energy/Noether's_Theorem_for_Energy

Thanks
Bill
 

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