BEISER MODERN PHYSICS Rotational Energy Level

Click For Summary
SUMMARY

The discussion focuses on calculating the distance between hydrogen and chlorine nuclei in an HCl molecule using the rotational spectrum wavelengths provided. The wavelengths given are 12.03 x 10-5 m, 9.60 x 10-5 m, 8.04 x 10-5 m, 6.89 x 10-5 m, and 6.04 x 10-5 m. The participant questions the application of the energy equation E = hc/λ for only one wavelength to determine the moment of inertia and expresses difficulty in obtaining the correct answer using the reduced mass method.

PREREQUISITES
  • Understanding of rotational spectroscopy and energy levels
  • Familiarity with the equation E = J(J+1)h2/(2I)
  • Knowledge of reduced mass calculations
  • Basic principles of quantum mechanics related to molecular rotation
NEXT STEPS
  • Study the derivation and application of the rotational energy levels in diatomic molecules
  • Learn about the concept of moment of inertia in molecular physics
  • Explore the calculation of reduced mass in diatomic systems
  • Investigate the relationship between wavelength and energy in quantum mechanics
USEFUL FOR

Students and professionals in physics, particularly those studying molecular spectroscopy, quantum mechanics, and rotational dynamics of diatomic molecules.

MARX
Messages
49
Reaction score
1

Homework Statement


  1. The rotational spectrum of HCl contains the following wavelengths:

    12.03 10 5 m 9.60 10 5 m 8.04 10 5 m 6.89 10 5 m 6.04 10 5 m

    If the isotopes involved are 1H and 35Cl, find the distance between the hydrogen and chlorine nuclei in an HCl molecule.

Homework Equations


E = J(J+1)h^2/(2I)[/B]

The Attempt at a Solution



I have the solution it says I have to use the difference in the frequency of above data
HERE IS MY QUESTION
why can't I apply the energy equation and use ONLY one of the wavelengths (E= hc/λ) to get the moment of inertia we know for longest λ above lowest energy hence J=0 There no
from there I know how to go from E to R using reduced mass
but that's not giving me the right answer [/B]
 
Physics news on Phys.org
MARX said:
why can't I apply the energy equation and use ONLY one of the wavelengths (E= hc/λ) to get the moment of inertia we know for longest λ above lowest energy hence J=0 There no
from there I know how to go from E to R using reduced mass
but that's not giving me the right answer
What answer to you get?
 

Similar threads

Replies
15
Views
2K
Replies
1
Views
6K
  • · Replies 4 ·
Replies
4
Views
6K
Replies
1
Views
2K
Replies
7
Views
2K
Replies
5
Views
3K
  • · Replies 3 ·
Replies
3
Views
3K
  • · Replies 5 ·
Replies
5
Views
2K
  • · Replies 8 ·
Replies
8
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K