Born-Haber Cycle: Formation of a Chlorine Atom

  • Thread starter Thread starter henry3369
  • Start date Start date
  • Tags Tags
    Cycle
Click For Summary
SUMMARY

The discussion focuses on the Born-Haber cycle, specifically the formation of a chlorine atom from a chlorine molecule. The reaction is represented as (1/2)Cl2 → Cl(g) with a ΔH of +122 kJ, which is derived from halving the bond energy of Cl2 (244 kJ). This halving is explained by the need to consider moles, where one mole of Cl2 produces two moles of Cl atoms, thus requiring only half the energy for the formation of a single chlorine atom.

PREREQUISITES
  • Understanding of the Born-Haber cycle
  • Knowledge of bond energy concepts
  • Familiarity with thermodynamic principles
  • Basic mole calculations in chemistry
NEXT STEPS
  • Study the Born-Haber cycle in detail
  • Learn about bond energies and their calculations
  • Explore thermodynamic equations related to enthalpy changes
  • Investigate mole concept applications in chemical reactions
USEFUL FOR

Chemistry students, educators, and professionals interested in thermodynamics and atomic formation processes.

henry3369
Messages
194
Reaction score
0

Homework Statement


I don't actually need help with an entire problem, I just can't seem to figure out what goes on when an atom is formed from a molecule in a Born-Haber cycle.

For example:
The formation of a chlorine atom from a chlorine molecule
(1/2)Cl2 → Cl(g) ΔH = (1/2) x bond energy of Cl2 = +122 kJ

Homework Equations

The Attempt at a Solution


Why is the bond energy being halved? It you have a Cl2 molecule, and you need 244 kJ to break the bond into two Cl atoms. Why would the formation of a Cl atom be only half of that then?
 
Physics news on Phys.org
Doesn't that (1/2) factor mean something?
 
Here, it might be more useful to think in terms of moles. Reacting one mole of Cl2 takes 244 kJ, and making one mole of chlorine atoms requires reacting 0.5 moles of Cl2.
 

Similar threads

  • · Replies 6 ·
Replies
6
Views
4K
  • · Replies 2 ·
Replies
2
Views
2K
Replies
2
Views
3K
Replies
6
Views
4K
  • · Replies 1 ·
Replies
1
Views
2K
Replies
3
Views
3K
  • · Replies 3 ·
Replies
3
Views
13K
Replies
2
Views
14K
  • · Replies 4 ·
Replies
4
Views
5K
  • · Replies 1 ·
Replies
1
Views
7K