The discussion centers on whether the boundary of an open set in n-dimensional space has Lebesgue measure zero. It is confirmed that while open sets typically have boundaries of measure zero, exceptions exist, particularly when considering Jordan-measurability. References are made to Spivak's calculus on manifolds, which illustrates that certain open sets can have boundaries with positive measure. An example provided involves constructing an open set from intervals around rational numbers, leading to a boundary with positive Lebesgue measure. The conversation highlights the nuances in measure theory regarding open sets and their boundaries.