Buffer/acid base titration question

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SUMMARY

This discussion focuses on the titration of a weak acid (HA) with a strong base (NaOH) and the behavior of the resulting buffer solution. The pH before the equivalence point is calculated using the buffer equation, as HA and its conjugate base (A-) coexist in solution. The Na+ ion from NaOH acts as a spectator ion and does not participate in any reaction with A-, which is why the system does not behave like a strong acid-strong base neutralization. The participants clarify that the presence of both HA and A- does not lead to a change in pH, as their interaction merely regenerates the weak acid and conjugate base.

PREREQUISITES
  • Understanding of weak acids and strong bases in acid-base chemistry
  • Familiarity with buffer solutions and their properties
  • Knowledge of dissociation and spectator ions in aqueous solutions
  • Basic grasp of chemical equilibrium concepts
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  • Study the Henderson-Hasselbalch equation for buffer calculations
  • Explore the concept of acid-base equilibrium and its applications
  • Learn about the role of spectator ions in chemical reactions
  • Investigate the differences between strong and weak acid-base titrations
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Chemistry students, educators, and anyone looking to deepen their understanding of acid-base titration and buffer chemistry.

LogicX
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Lets say you titrate a weak acid, HA, with a strong base, NaOH.

Now, before the equivalence point, the pH is calculated like a buffer because HA + OH- -> A- + H2O. So you have a mixture of a an acid and its conjugate base. My question is, why doesn't this act like a neutralization reaction like a strong acid and strong base? In order to get OH- you have to dissociate NaOH, so you also have Na+ in solution. Why doesn't the Na+ react with the A- to form a salt like a strong acid and strong base would?

I'm also confused about buffers in general. You have an acid and its conjugate base... why don't they react? How can they coexist in solution?

Help, I seem to have a fundamental misunderstanding of acid-base chemistry!

EDIT:

WOW I'm dumb. I've been stressing over this for hours, thinking I didn't understand chemistry anymore. But obviously, the A- is in solution so its not going to form a precipitate because salts dissociate in water. Na+ is just a spectator ion.

Still not totally sure on the second question though.

Well, actually I guess they couldn't really react and change pH. If HA reacts with A- it would just form another A-...
 
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Chemistry news on Phys.org
You are right on both counts. There is a dissolved salt in the solution in both cases, and when weak acid reacts with its conjugate base products are weak acid and conjugate base - so nothing changes.
 
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