Calculate \Delta H_{rxn}\circ for 2Al_{2}O_{3} to 4Al+3O_{2}

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SUMMARY

The discussion centers on calculating the standard enthalpy change (\Delta H_{rxn}\circ) for the reaction 2Al_{2}O_{3}(s) → 4Al + 3O_{2}(g). The standard enthalpy of formation (\Delta H_{f}\circ) for Al_{2}O_{3} is -1670 kJ/mol. To find \Delta H_{rxn}\circ, the value is multiplied by 2, resulting in -3340 kJ/mol. However, since the reaction direction is reversed, the sign changes, yielding a final result of +3340 kJ/mol, indicating an endothermic reaction.

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[tex]\Delta H_{f}\circ[/tex]=-1670kJ/mol for [tex]Al_{2}O_{3}[/tex]

What is [tex]\Delta H_{rxn}\circ[/tex] for
[tex]2Al_{2}O_{3}(s)\rightarrow4Al+3O_{2}(g)[/tex]

So clearly we simply multiply -1670*2=-3340kJ/mol.

The answer is actually POSITIVE 3340kJ/mol!

Can someone please explain to me how this reasoning works?

Thank you!
 
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You reverse the reaction direction, so you need to reverse the sign. If reaction is exothermic when going one side, it must be endothermic when going back.
 

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