Calculate heat released in the reaction

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SUMMARY

The discussion focuses on calculating the heat released during a combustion reaction involving substances A, B, C, and D at 300K. The combustion enthalpies are provided: ΔH A = -1000 cal/mol, ΔH B = -2000 cal/mol, ΔH C = -500 cal/mol, and ΔH D = -100 cal/mol. The heat released for the reaction is determined to be ΔH of reaction = 2400 cal/mol, leading to a calculated ΔQ of 1800 cal/mol at constant volume. However, the user identifies a misunderstanding regarding the calculation of ΔQ per mole.

PREREQUISITES
  • Understanding of combustion reactions and enthalpy changes
  • Familiarity with the concept of constant volume in thermodynamics
  • Knowledge of first-order reaction kinetics
  • Basic proficiency in thermodynamic equations, specifically ΔH and ΔU
NEXT STEPS
  • Study the calculation of ΔQ in thermodynamic processes
  • Learn about first-order reaction kinetics and its implications on heat release
  • Explore the relationship between ΔH, ΔU, and Δng in chemical reactions
  • Investigate the impact of temperature on combustion enthalpies
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Chemistry students, thermodynamics enthusiasts, and professionals involved in chemical reaction engineering or energy calculations will benefit from this discussion.

utkarshakash
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Homework Statement


All the substances involved in the reaction given below can undergo combustion reaction and their combustion enthalpies at 300K are given below,
2A(g)+B(g) ----> 3C(g) + D(g)
Given: ΔH A = -1000cal/mol ΔH B= -2000cal/mol ΔH C=-500 cal/mol ΔH D = -100 cal/mol
If the reaction occurs at constant volume at 300K and the reaction obeys first order with respect to A and if A reduces to half its initial amount in 69.3 sec, then calculate

1) heat released when 2*10-3 mole of A has reacted at 300K(in cal)

2) rate at which heat is released initially, if initially 1mol of A is present.


The Attempt at a Solution



ΔH of rxn = 2400 cal/mol
ΔH = ΔU + Δng RT
Since the reaction occurs at constant volume ΔQ = ΔU
ΔQ = ΔH - Δng RT

Substituting appropriate values , I get ΔQ = 1800 cal/mol. But this is not the correct answer.
 
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Where does it ask for ΔQ PER MOLE??
 

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