Calculate pH of CH3COOH & NaOH Solution

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The discussion focuses on calculating the pH of a solution created by mixing 200 mL of 0.2 M acetic acid (CH3COOH) with 100 mL of 0.1 M sodium hydroxide (NaOH). The strong base NaOH completely converts acetic acid to acetate, necessitating the use of the Henderson-Hasselbalch equation for pH calculation. Participants emphasize the importance of determining the concentrations of the weak acid and its conjugate base after the reaction, suggesting the use of ICE tables for clarity, although a direct application of the Henderson-Hasselbalch equation is deemed sufficient for this scenario.

PREREQUISITES
  • Understanding of weak acids and strong bases
  • Familiarity with the Henderson-Hasselbalch equation
  • Knowledge of ICE (Initial, Change, Equilibrium) tables
  • Basic skills in concentration calculations
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  • Study the Henderson-Hasselbalch equation in detail
  • Practice setting up ICE tables for acid-base reactions
  • Learn about buffer solutions and their properties
  • Explore examples of pH calculations involving weak acids and strong bases
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Chemistry students, particularly those preparing for exams involving acid-base equilibria, and educators seeking to enhance their teaching of buffer systems and pH calculations.

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A solution is prepared by mixing 200 mL of 0.2 M CH3COOH with 100 mL of 0.1 M of NaOH solution.Calculate the pH of the solution.(Ka=1.8x10-5)

I really don't know how to start this, so please help me.Its going to be a similar one on my exam tomorrow.

Thanks.
 
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Assume the strong base completely converts the acetic acid to acetate. From there look at the expression which defines Ka for this acid. That's a start.

If you can't see it from that information, try looking over this information.
 
Hint: have you heard about buffers?
 
This is a buffer question. You will need to set up two ICE tables. The first one outlines the remaining concentration of weak acid and conjugate base after the reaction with OH-. The second should use those concentrations to determine the final pH. If you have a book, there should be an example.
 
Actually no need even for a single ICE table, this is almost a simple plug and chug application of the Henderson-Hasselbalch equation. You just need to start calculating concentrations of the reaction products, assuming reaction went to completion.
 
Correct, the Henderson-Hasselbalch equation is the preferred method. If this student does not know where to start, however, I figured writing out the concentration ratios would help in gaining some intuition.
 

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