Calculate the pH of a solution made by dissolving 10.6 g caffeine

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SUMMARY

The discussion focuses on calculating the pH of a solution created by dissolving 10.6 g of caffeine (C8H10N4O2) in 100 mL of water. The participant initially calculated the concentration as 0.5458 M and attempted to derive the pH using the base dissociation constant (Kb) of caffeine, which is 4.1 x 10-4. However, the participant made an error in the calculation of Kb, incorrectly applying the formula for Kb instead of using the provided value directly, leading to an incorrect pH result of 8.56.

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  • Understanding of weak bases and their dissociation constants (Kb)
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  • Familiarity with pH and pOH calculations
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  • Review the calculation of pH for weak bases using the provided Kb value
  • Learn about the relationship between pH, pOH, and the ion product of water (Kw)
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  • Explore common mistakes in acid-base equilibrium calculations
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Chemistry students, educators, and anyone involved in acid-base chemistry or solution preparation will benefit from this discussion.

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Homework Statement



Calculate the pH of a solution made by dissolving 10.6 g caffeine (C8H10N4O2, a weak base, Kb = 4.1 x 10-4) in enough water to make 100. mL of solution.

Homework Equations


pH = -log [H3O+]
kb = kw/ka


The Attempt at a Solution



I first found conc.:
MM= 194.2
m = 10.6
n = 0.05458 mol
conc. = 0.5458

kb = (10^-14)/ (4.1 x 10-4)
= 2.439*10^11

kb= x^2 / 0.5458
... x = 3.64 *10^-6
pOH = -log pOH
pH = 14 - pOH
= 8.56

But this is wrong... where did I go wrong?
 
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a.a said:
kb = (10^-14)/ (4.1 x 10-4)

You were already given Kb.
 

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