Calculate the theoretical yield percentage for this reaction

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SUMMARY

The discussion focuses on calculating the theoretical yield percentage of silicon (Si) from an impure starting material. The conversion of 1.0 ton of impure silicon to silicon tetrachloride (SiCl4) is analyzed, with specific atomic masses provided: Si at 28.085 g/mol and Cl2 at 70.906 g/mol. The theoretical moles of Si and SiCl4 are calculated as 3.6x10^4 mol and 1.4x10^4 mol, respectively. A critical point raised is the need to account for the purity of the starting material, which contains 92% Si, before proceeding to yield calculations.

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  • Understanding of stoichiometry in chemical reactions
  • Knowledge of molar mass calculations
  • Familiarity with yield percentage calculations
  • Basic concepts of purity in chemical substances
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  • Calculate the actual mass of silicon in 1.0 ton of impure material using the purity percentage.
  • Determine the theoretical yield of SiCl4 based on the adjusted mass of silicon.
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Kiah Palmer
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Homework Statement
In the first step of silicon purification, a reaction is brought about between the impure silicon and chlorine. Pure silicon is then used, in the computer industry, for the manufacture of microchips.

Si + Cl2 -> SiCl4 (unbalanced equation)

Given that the silicon is 92% pure, calculate the theoretical yield percentage if 1.0 t of impure silicon produces 2.33 t of silicon (IV) chloride.
Relevant Equations
(Balanced Equation) Si + 2Cl2 -> SiCl4
Conversion: 1.0 t = 1.0x10^6 g impure Si
Conversion: 2.33 t = 2.33x10^6 g SiCl4
Atomic Mass Si = 28.085 g/mol
Atomic Mass Cl2 = (2 x 35.453) = 70.906 g/mol
Mass SiCl4 = 28.085 + (4x35.453) = 169.897 g/molI got all this part down, however, I'm not quite sure where I am supposed to go from there...
 
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How much silicon is there in 1.0 t of the starting material? How much SiCl4 would you expect to make from it?
 
so for that, I would need to find Mol Si and mol SiCl4, which I believe is as follows:

Theoretical # mol Si = 1.0x10^6 g / 28.085 g/mol = 3.6x10^4 mol

Theoretical # Mol SiCl4 = 2.33x10^6 g / 169.897 g/mol = 1.4x10^4 mol

I think this would be correct for the # mol (if that was even needed) But I am still a bit confused as to what I would do next. Is this where the equation to find the theoretical yield percentage would go?? Or is there steps in between missing still?
 
Last edited:
Kiah Palmer said:
Theoretical # mol Si = 1.0x10^6 g / 28.085 g/mol = 3.6x10^4 mol

No. You don't have a ton of Si. You have a ton of a material which contains 92% Si.
 
Borek said:
No. You don't have a ton of Si. You have a ton of a material which contains 92% Si.
Ok, so then I would need to use Mol SiCl4 then calculate the yield percent? Or do I need to find out what 92% of the mass of Si would be first, then recalculate mol?
 
See my first post in the thread, it addresses exactly questions you are asking now.
 

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