Calculate the theoretical yield percentage for this reaction

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Discussion Overview

The discussion revolves around calculating the theoretical yield percentage for a chemical reaction involving silicon and silicon tetrachloride (SiCl4). Participants are exploring the necessary steps and calculations required to determine the yield from an impure starting material.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Technical explanation

Main Points Raised

  • One participant provides initial conversions and atomic masses relevant to the reaction but expresses uncertainty about the next steps.
  • Another participant asks for clarification on the amount of silicon in the starting material and the expected amount of SiCl4 produced.
  • A participant calculates the theoretical number of moles of silicon and SiCl4 but questions the necessity of these calculations for determining the yield percentage.
  • One participant corrects the assumption that the entire mass is pure silicon, indicating that the starting material contains only 92% silicon.
  • There is a suggestion to either calculate the yield percentage using the moles of SiCl4 or to first determine the mass of silicon based on its percentage in the starting material before recalculating moles.
  • A later reply refers back to the initial post to address ongoing questions about the calculations.

Areas of Agreement / Disagreement

Participants do not appear to reach a consensus on the correct approach to calculate the theoretical yield percentage, with multiple views on how to proceed based on the purity of the starting material.

Contextual Notes

There are unresolved assumptions regarding the purity of the starting material and how it affects the calculations for theoretical yield. Participants have not fully clarified the necessary steps to transition from moles to yield percentage.

Kiah Palmer
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Homework Statement
In the first step of silicon purification, a reaction is brought about between the impure silicon and chlorine. Pure silicon is then used, in the computer industry, for the manufacture of microchips.

Si + Cl2 -> SiCl4 (unbalanced equation)

Given that the silicon is 92% pure, calculate the theoretical yield percentage if 1.0 t of impure silicon produces 2.33 t of silicon (IV) chloride.
Relevant Equations
(Balanced Equation) Si + 2Cl2 -> SiCl4
Conversion: 1.0 t = 1.0x10^6 g impure Si
Conversion: 2.33 t = 2.33x10^6 g SiCl4
Atomic Mass Si = 28.085 g/mol
Atomic Mass Cl2 = (2 x 35.453) = 70.906 g/mol
Mass SiCl4 = 28.085 + (4x35.453) = 169.897 g/molI got all this part down, however, I'm not quite sure where I am supposed to go from there...
 
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How much silicon is there in 1.0 t of the starting material? How much SiCl4 would you expect to make from it?
 
so for that, I would need to find Mol Si and mol SiCl4, which I believe is as follows:

Theoretical # mol Si = 1.0x10^6 g / 28.085 g/mol = 3.6x10^4 mol

Theoretical # Mol SiCl4 = 2.33x10^6 g / 169.897 g/mol = 1.4x10^4 mol

I think this would be correct for the # mol (if that was even needed) But I am still a bit confused as to what I would do next. Is this where the equation to find the theoretical yield percentage would go?? Or is there steps in between missing still?
 
Last edited:
Kiah Palmer said:
Theoretical # mol Si = 1.0x10^6 g / 28.085 g/mol = 3.6x10^4 mol

No. You don't have a ton of Si. You have a ton of a material which contains 92% Si.
 
Borek said:
No. You don't have a ton of Si. You have a ton of a material which contains 92% Si.
Ok, so then I would need to use Mol SiCl4 then calculate the yield percent? Or do I need to find out what 92% of the mass of Si would be first, then recalculate mol?
 
See my first post in the thread, it addresses exactly questions you are asking now.
 

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