To calculate the pH of a 350L solution of sulfuric acid (H2SO4) with a hydrogen ion concentration of 2.0 x 10^-4 mol/L, the pH is determined using the formula pH = -log[H3O+], resulting in a pH of approximately 3.69. The discussion highlights the importance of considering the concentration of sulfuric acid and the dissociation of water, especially at low concentrations. For neutralization, the stoichiometry of the reaction between sulfuric acid and sodium hydroxide (NaOH) is crucial, with the balanced equation being 2 NaOH + H2SO4 → Na2SO4 + 2 H2O. The calculated mass of NaOH needed for neutralization is approximately 2.8g. Overall, the conversation emphasizes the need for careful consideration of concentration and stoichiometry in acid-base reactions.