Can Diatomic Helium Molecules Be Created through Ionizing Radiation?

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SUMMARY

Diatomic helium molecules (He2) can be formed under specific conditions, primarily through ionizing radiation, which can produce He2+ ions and electronically excited states (He2*). However, He2 is only stable as a van der Waals molecule at very low temperatures, existing in molecular beams with a weak bond and significant interatomic spacing. The formation of He2 requires careful control of environmental conditions, particularly in condensed phases or during specific expansions like the Joule-Thomson (JT) effect.

PREREQUISITES
  • Understanding of ionizing radiation and its effects on atomic structures
  • Knowledge of molecular bonding, particularly van der Waals forces
  • Familiarity with low-temperature physics and molecular beams
  • Concepts related to electronically excited states in molecules
NEXT STEPS
  • Research the effects of ionizing radiation on helium atoms
  • Explore the properties and formation conditions of van der Waals molecules
  • Study low-temperature molecular beam techniques
  • Investigate the Joule-Thomson effect and its applications in molecular physics
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Physicists, chemists, and researchers interested in molecular formation, particularly those studying exotic molecules and the effects of ionizing radiation on atomic interactions.

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Could you make a diatomic helium molecule?

Say you passed ionizing radiation through helium would these ions join to form He2 . I'm not sure wether this would produce an unstable balance of charges in the molecule?
 
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You can make a bound molecule of He2+. You can also make He2*, where * indicates an electronically excited state, but as far as I know you can only make that molecule in condensed phases, or perhaps in the warm part of a JT expansion.

Neutral He2 exists as a van der Waals molecule in very low temperature molecular beams. It is a very exotic molecule, with an extremely weak bond, and an average interatomic spacing of tens of Angstroms.
 

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