Can Magnets Attract H2O Molecules?

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SUMMARY

Water (H2O) is not magnetic in the traditional sense; it is classified as diamagnetic, meaning it exhibits a very weak repulsion to magnetic fields. While water does interact with strong magnetic fields due to its paramagnetic properties, this is primarily because of the unpaired electrons in the oxygen atom's p orbitals. The confusion often arises when comparing water to oxygen (O2), which is paramagnetic due to its two unpaired electrons. Therefore, water lacks a permanent magnetic moment, distinguishing it from ferromagnetic materials like cobalt-iron-neodymium.

PREREQUISITES
  • Understanding of molecular polarity and dipole moments
  • Familiarity with electron configurations and atomic orbitals
  • Knowledge of magnetic properties: diamagnetism vs. paramagnetism
  • Basic principles of electromagnetism and magnetic fields
NEXT STEPS
  • Research the differences between diamagnetic and paramagnetic materials
  • Explore the concept of magnetic moments in various substances
  • Learn about the Gouy balance and its applications in measuring magnetic susceptibility
  • Investigate the role of unpaired electrons in determining magnetic properties of molecules
USEFUL FOR

Chemists, physicists, and students studying molecular chemistry and magnetism will benefit from this discussion, particularly those interested in the magnetic properties of water and other substances.

mapa
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I understand that H2O is polarized. The way I see it there is a north pole and a sole pole. If this is correct, why does it not attract magnets?
 
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Thanks for the help.
 
H2O is really not truly magnetic. When you say "magnetic" you probably mean "ferromagnetic" or that it has a permanent magnetic moment. Water can't, because there's no "spot" where unpaired electrons could permanently "live".

Water is paramagnetic, which means that it has a slight magnetic moment, because the last two electrons in oxygen's shell are unpaired and each one is in the p_x* and p_y* orbitals. You can measure this in something called a "gouy balance" - same thing w/ O2 gas or O2 liquid. There's a ton of switching around of these electrons (note the "*", meaning they are in special "antibonding" orbitals), so that's why you only get a very mild, impermanent magnetic moment.

Water has a "big" electric dipole moment, however, b/z oxygen is so electronegative, that the bulk of the time the electrons that came along with, and are covalently shared by, the two hydrogens, spend their time around oxygen.

In solids, where lots of unpaired electrons can permanently live in the crystalline unit cells of compounds like cobalt-iron-neodymium or what have you, can and do have very large permanent magnetic moments...all the unpaired electrons EACH occupy a d-orbital...since they're all pointing in one direction (due to Hund's rules and the Aufbau principle), there's your permanent magnetic moment and, hence, ferromagnetism. Does that help?
 
solidspin said:
Water is paramagnetic, which means that it has a slight magnetic moment, because the last two electrons in oxygen's shell are unpaired and each one is in the p_x* and p_y* orbitals.

I'm afraid you've confused water with O2 and atomic orbitals with molecular ones.
Water has no unpaired electrons and is thus diamagnetic. Which, (for the benefit of the original poster), means it's even less magnetic than that - about as un-magnetic as a substance can get.

It's O2 that has two unpaired electrons (in the \pi^*_x and \pi^*_y molecular orbitals), and is thus paramagnetic.
 

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