Can Raman spectroscopy identify every substance?

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SUMMARY

Raman spectroscopy can theoretically identify all substances due to the presence of active Raman modes in all point groups. However, the effectiveness of detection is contingent upon the magnitude of these modes, which may be too small to measure in certain cases. Monatomic gases, such as noble gases, are generally transparent to Raman spectroscopy unless adsorbed onto a surface, where spectra can be observed. Liquid state studies present additional challenges in obtaining clear Raman spectra.

PREREQUISITES
  • Understanding of Raman spectroscopy principles
  • Knowledge of molecular rotational and vibrational states
  • Familiarity with point group symmetry in chemistry
  • Experience with sample preparation for liquid state spectroscopy
NEXT STEPS
  • Research methods for enhancing Raman signal detection
  • Learn about sample preparation techniques for liquid Raman spectroscopy
  • Explore the limitations of Raman spectroscopy with monatomic gases
  • Investigate the role of surface adsorption in Raman spectroscopy
USEFUL FOR

Chemists, materials scientists, and researchers involved in spectroscopy who seek to understand the capabilities and limitations of Raman spectroscopy in identifying various substances.

David lopez
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Can raman spectroscopy identify any substance or are there certain
Substances raman spectroscopy cannot identify?
 
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in theory, yes. All point groups have active Raman modes, but the magnitude may not be large enough to measure.
 
What substances have raman modes
Too small to measure?
 
If somebody built a raman spectroscopy, is there any reason 5 milliwatts would be inadequate for this
Application?
 
Dr Transport said:
in theory, yes. All point groups have active Raman modes, but the magnitude may not be large enough to measure.

When you write "In theory, yes", will the OP have realized that you're answer applies only to bound substances with rotational and vibrational states: mainly molecules and solids (point groups)?

Obtaining raman spectra in liquid state studies can be difficult: https://www.researchgate.net/post/How_to_prepare_liquid_sample_for_Raman_spectrometer_to_get_good_spectrum

But unless they display very-low-energy electronic transitions, I would expect monatomic gases such as noble gases to be completely transparent to raman spectroscopy (except when adsorbed onto a surface, in which case such spectra have been observed, e.g. https://www.semanticscholar.org/pap...hita/ce681015459750bb4dfc4882d3d125b2b5869046).

Regards - P
 

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