Capacitance Comparison for Spherical Shells and Solid Spheres

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theneedtoknow
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Would the capacitance of the system be the same if we had one spherical shell around another (radii a and b) , versus a solid sphere of radius a surrounded by shell of radius b? I mean...if the charge we add to the solid sphere distributes itself completely on the surface, isn't the inner solid sphere going to act exactly like a thin shell with the radius of the sphere?
 
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Thank you :) And, is there another way to calculate the capacitance of such a system other than C=Q/V ?
 
You can derive an expression for the capacitance. See
http://www.mwit.ac.th/~physicslab/hbase/electric/capsph.html