Carnot's Theorem & Irreversible Heat Engines

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SUMMARY

Carnot's theorem establishes that all irreversible heat engines operating between two heat reservoirs are less efficient than a Carnot engine functioning between the same reservoirs. The discussion highlights a proof involving an irreversible heat engine driving a Carnot refrigerator, referencing M. Zemansky and R. Dittman's "Heat and Thermodynamics" (1997). The efficiency equations for both the refrigerator and the heat engine are clarified, emphasizing that the efficiency of a refrigerator, defined as η=QL/W, aligns with the principles of Carnot engines. The discussion concludes that the efficiency of a Carnot engine remains consistent regardless of its operational direction.

PREREQUISITES
  • Understanding of Carnot's theorem
  • Familiarity with thermodynamic efficiency equations
  • Knowledge of heat engines and refrigerators
  • Basic principles of thermodynamics
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  • Study the derivation of Carnot's theorem in detail
  • Explore the efficiency calculations for various types of heat engines
  • Learn about the implications of irreversible processes in thermodynamics
  • Investigate real-world applications of Carnot engines and refrigerators
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Students of thermodynamics, engineers working with heat engines, and researchers interested in the efficiency of thermal systems will benefit from this discussion.

nikolafmf
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(Part of the) Carnot's theorem:

"All irreversible heat engines between two heat reservoirs are less efficient than a Carnot engine operating between the same reservoirs."

is proved with irreversible heat engine driving Carnot refrigerator. In the proof (for example M. Zemansky, R. Dittman, Heat and Thermodynamics, 1997, page 175) it is used for efficiency of the refrigerator: η=W/QH, W is work done to refrigerator, QH is heat given to hotter reservoir. But this equation is true for the heat engine, where W would be work done by engine and QH heat taken from the hotter engine. For refrigerator, efficiency, as far as I know, is η=QL/W, where W is work done to refrigerator, QL is heat taken from colder reservoir. Where is my mistake, if any?
 
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a refrigerator is actually a carnot engine working in the opp. direction.hence the expression for efficiency of a refrigerator(as a heat engine not a cooling machine)is same as that of a regular carnot heat engine.
 

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And why efficiency of Carnot engine working in the opposite direction is the same as efficiency of Carnot engine working in the "normal" direction?
 

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