Catalytic decomposition of nitrous oxide?

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SUMMARY

The discussion focuses on the catalytic decomposition of nitrous oxide (N2O) into nitrogen (N2) and oxygen (O2), emphasizing the need for suitable materials to lower activation energy. Platinum, palladium, and rhodium are identified as effective catalysts, with platinum being the most active but costly and limited in some applications. The melting points of these metals are provided, highlighting their thermal stability: Rhodium at 2237 K, Palladium at 1828 K, and Platinum at 2041 K. The conversation also notes the legal restrictions on using nickel and copper in certain regions due to environmental concerns.

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  • Understanding of catalytic processes and their applications
  • Knowledge of precious metals used in catalysis, specifically platinum, palladium, and rhodium
  • Familiarity with the thermal properties of metals, including melting points
  • Awareness of environmental regulations regarding catalyst materials
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  • Research the properties and applications of platinum group metals in catalysis
  • Learn about the Fischer-Tropsch synthesis and its catalysts
  • Investigate alternative catalysts for N2O decomposition that are cost-effective and environmentally compliant
  • Explore the legal implications of using specific metals in catalytic converters in different regions
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Chemists, environmental engineers, and professionals involved in catalytic converter design and optimization will benefit from this discussion.

rocketman
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Does anyone know what types of materials may be used to decrease the activation energy of 2N_2O->2N_2 +O_2. I think perhaps silver may work, but I need to find a material which will withstand the high temperature of decomposition

thanks
 
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Platinum, palladium and rhodium are two metals that serve as catalysts converting NOx to nitrogen and oxygen.

http://en.wikipedia.org/wiki/Catalytic_converter#Purpose_and_function_of_catalytic_converters

http://en.wikipedia.org/wiki/Catalytic_converter

The catalyst itself, most often a precious metal. Platinum is the most active catalyst, and is widely used. However, it is not suitable for all applications because of unwanted additional reactions and/or cost. Palladium and rhodium are two other precious metals that are used, Palladium as a substitute for Platinum in three-way catalytic converters, and Rhodium is the material that makes a three-way reaction possible. Cerium, iron, and nickel are also used, though each has its own limitations. Nickel is not legal for use in the European Union (nickel hydrate formation). While copper can be used, its use is illegal in North America due to the formation of dioxin.
Wikipedia

Other references:

http://www.schoolscience.co.uk/content/5/chemistry/catalysis/catsch3pg11.html

http://www.chemistry.org/portal/a/c/s/1/feature_ent.html?id=9a4f4f92320b11d7f4a56ed9fe800100
 
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Do you know the melting point of any of these catalysts? The decomposition of NOX can serve as a gas generator, creating oxygen and nitrogen, and can thermally sustain itself in the presence of a catalyst with relatively little activation energy. I would like to find a way to cost effectively decompose NOX into its constituants in an adiabatic reaction for the purposes of 1) heating and expanding the flow, and 2) creating free oxygen. I knew of the precious metal approach, but it seems a bit fiscally difficult. Also, I may be mistaken but I believe N2O is not a major byproduct of car emmissions such as NO or NO2 and various other oxygen rich nitrogen oxides.
 
Melting temperatures for the elements can be found at www.webelements.com

Rh is in the same group as Co.

Co, 1768 K [or 1495 °C (2723 °F)]
Rh, 2237K [or 1964 °C (3567 °F)]

Pd and Pt are in the Ni group.

Ni, 1728 K [or 1455 °C (2651 °F)]
Pd, 1828.05 K [or 1554.9 °C (2830.82 °F)]
Pt, 2041.4 K [or 1768.3 °C (3214.9 °F)]

Cu, 1357.77 K [or 1084.62 °C (1984.32 °F)]

Co and Cu are used in Fischer-Tropsch synthesis in which H2 and CO are combined to form alkanes or alkenes.

BTW, NOx generally refers to NO and NO2.
 
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