A rotation of 45° clockwise about the origin sends the point $(x,y)$ to the point $(X,Y)$, where
$$\begin{pmatrix}X \\ Y\end{pmatrix}\ =\ \begin{pmatrix}\frac1{\sqrt2} & \frac1{\sqrt2} \\ -\frac1{\sqrt2} & \frac1{\sqrt2}\end{pmatrix}\begin{pmatrix}x \\ y\end{pmatrix}\ =\ \begin{pmatrix}\frac{x+y}{\sqrt2} \\ \frac{-x+y}{\sqrt2}\end{pmatrix}.$$
Thus the rotation takes the curve
$$\frac{-x+y}{\sqrt2}\ =\ e^{\frac{x+y}{\sqrt2}}$$
to the curve
$$Y\ =\ e^X.$$
The 45° tangent to the latter curve is the line $Y=X+1$. Rotating this 45° counterclockwise about the origin gives
$$\frac{-x+y}{\sqrt2}\ =\ \frac{x+y}{\sqrt2}\,+\,1$$
$\implies\ x\ =\ -\dfrac1{\sqrt2}$.