Chemistry, Calorimetry finding delta H

Click For Summary
SUMMARY

The discussion focuses on calculating the enthalpy change (ΔH) for the reaction between sodium metal and water, represented by the equation 2 Na(s) + 2 H2O(l) → 2 NaOH(aq) + H2(g). Given that 0.030 mol of sodium is added to water, resulting in a temperature increase from 25.00°C to 37.90°C in a calorimeter with a heat capacity of 400 J/°C, the participant correctly identifies that the heat absorbed by the calorimeter (q) can be calculated using q = CΔT. The participant concludes that ΔH can be determined using the formula q = nΔH, where n is the number of moles of sodium.

PREREQUISITES
  • Understanding of calorimetry principles
  • Knowledge of the heat capacity formula (q = CΔT)
  • Familiarity with the concept of enthalpy change (ΔH)
  • Basic stoichiometry involving moles in chemical reactions
NEXT STEPS
  • Calculate ΔH for the sodium and water reaction using the provided data
  • Explore advanced calorimetry techniques for different reaction types
  • Study the relationship between enthalpy and reaction stoichiometry
  • Review common calorimetry problems and solutions for exam preparation
USEFUL FOR

Chemistry students, particularly those preparing for exams in thermodynamics and calorimetry, as well as educators looking for practical examples of enthalpy calculations.

alexpratt
Messages
18
Reaction score
0

Homework Statement



Sodium metal reacts with water to produce hydrogen gas and sodium hydroxide
according to the equation:
2 Na(s) + 2 H2O(l) ? 2 NaOH(aq) + H2(g)
When 0.030 mol of Na is added to water, the temperature of the calorimeter rises
from 25.00C to 37.90C. If the heat capacity of the calorimeter is 400 J/C,
calculate ?H for the reaction as written


Homework Equations



q_system=-q_surroundings
q=CdeltaT
q=ndeltaH (?)



The Attempt at a Solution



i haven't actually tried to work out the numbers because I am not given the answer and i won't know if I am right or wrong. I have some ideas though which I would like someone to validate for me!

i know i can find q for the calorimeter because I am give C for the calorimeter and the temperature change. And that q of the calorimeter is -q for everything else.
So, once i have q, would i plug that into q=ndeltaH solve that for deltaH and use .03 moles for the n value?

this is the only kind of calorimetry problem i have trouble with constantly, on top of that my final exam is in two hours :( shouldn't leave things til the last minute i suppose.

anyways, any help at all is appreciated! like i said, i don't expect you to do the problem for me, i was just wondering if i could be pointed in the right direction!
 
Physics news on Phys.org
alexpratt said:
2 Na(s) + 2 H2O(l) ? 2 NaOH(aq) + H2(g)

So, once i have q, would i plug that into q=ndeltaH solve that for deltaH and use .03 moles for the n value?

That would give you delta H per one mole of Na, the way reaction is written heat that evolves would be twice that (two moles of Na reacting).
 
ok, that makes sense thank you!

i had some other examples that i had the answer to and i noticed some of my answers were half of the right answer but i never made that connection. Unfortunately that question was on the exam :(

regardless thank you for your help, it'll come in handy next semester I am sure!
 

Similar threads

  • · Replies 12 ·
Replies
12
Views
3K
Replies
3
Views
4K
  • · Replies 8 ·
Replies
8
Views
3K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 9 ·
Replies
9
Views
3K
  • · Replies 2 ·
Replies
2
Views
4K
  • · Replies 16 ·
Replies
16
Views
3K
  • · Replies 2 ·
Replies
2
Views
4K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K