Chemistry: Finding a temperature change using a temperature/gram ratio

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SUMMARY

The discussion focuses on calculating the temperature change associated with the formation of magnesium chloride (MgCl2) from magnesium (Mg) and hydrochloric acid (HCl) in a calorimetry experiment. The reaction is represented by the equation Mg + 2HCl → MgCl2 + H2, with a measured temperature change of 25.5°C after mixing 0.5g of Mg with 115mL of HCl. The specific heat of water (c=4.184 J/g°C) is utilized to determine the heat of formation, but the initial calculations regarding the temperature change of 1 mol of MgCl2 were incorrect due to misunderstanding the question's requirements.

PREREQUISITES
  • Understanding of stoichiometry and limiting reactants in chemical reactions
  • Familiarity with calorimetry and the specific heat formula Q=cm(t2-t1)
  • Knowledge of molar mass calculations, specifically for MgCl2 (95.21 g/mol)
  • Basic algebra skills for manipulating equations and solving for unknowns
NEXT STEPS
  • Review the principles of calorimetry and how to calculate heat transfer in chemical reactions
  • Study the concept of molar enthalpy and its application in thermochemical equations
  • Learn about the role of limiting reactants in determining product yields in chemical reactions
  • Practice solving similar stoichiometry problems involving temperature changes and specific heat calculations
USEFUL FOR

Chemistry students, educators, and anyone involved in laboratory experiments related to thermodynamics and reaction enthalpy calculations.

Aiko
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Homework Statement


In this investigation, you mix .5g of Mg(s) with 115mL HCl. You measure the temperature change which turns out to be 25.5 degrees C. The equation is as follows:

Mg + 2HCL --> MgCl2 + H2

Use the specific heat of water (c=4.184) to find the heat of formation.

What is the temperature change of 1mol of MgCl2?

Homework Equations


Q=cm(t2-t1)
Kind of basic algebra that I think I'm getting wrong. Or maybe I'm using the wrong variables.

The Attempt at a Solution


This problem uses the specific heat of water. This means that we must use the mass of water as well (1mol = 18g).
Q=4.184(18g)(t2-t1)

I am having trouble with the temperature change. Mg is the limiting reactant. Therefore:

.5g Mg (mol/24.31g) = .021mol Mg (mol MgCl2/mol Mg) = .021mol MgCl2

.021mol MgCl2 (95.21g MgCl2/mol MgCl2) = 1.99941 ~2.00g MgCl2

Therefore:

(25.5C/2.00g MgCl2) * 95.21g MgCl2 = 1214C

This answer however, isn't correct. Am I supposed to use the masses of water instead?
 
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Temperature of _what_ has changed?
 
Aiko said:

Homework Statement


In this investigation, you mix .5g of Mg(s) with 115mL HCl. You measure the temperature change which turns out to be 25.5 degrees C. The equation is as follows:

Mg + 2HCL --> MgCl2 + H2

Use the specific heat of water (c=4.184) to find the heat of formation.

What is the temperature change of 1mol of MgCl2?

Can anyone help?
 
Can you answer the question asked in my previous post?

You are not asked about temperature change of 1 mol of MgCl2, you must have misread the question. This is a classic experiment for determination of molar enthalpy of the reaction.
 

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