Chloride test question (Mohr's method)

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SUMMARY

The discussion centers on the Mohr's method for chloride testing, utilizing potassium chromate and silver nitrate. A participant inquires about the disposal and potential recycling of silver nitrate after conducting the test. It is confirmed that while recycling silver from waste is possible, achieving a complete return to the original 5g of silver nitrate is not feasible. The conversation emphasizes the importance of adhering to local regulations regarding hazardous materials and suggests practical methods for handling silver chloride waste.

PREREQUISITES
  • Understanding of Mohr's method for chloride testing
  • Knowledge of potassium chromate and silver nitrate chemistry
  • Familiarity with hazardous material disposal regulations
  • Basic skills in chemical recycling techniques
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  • Research methods for recycling silver from silver chloride waste
  • Learn about local regulations for hazardous material disposal
  • Explore alternative chloride testing methods
  • Investigate the chemistry of silver nitrate and its applications
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Chemistry students, laboratory technicians, and hobbyists conducting experiments involving chloride testing and silver recycling.

skyshrimp
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I'm going to try my first chemistry experiment.

http://www.chemteach.ac.nz/investigations/documents/chloride_mohr.pdf

I bought 35g of potassium chromate and 5g of silver nitrate.

5g of silver nitrate is only enough for one test. What should I do with the silver afterwards? Is it possible to turn it back into 5g of silver nitrate to redo the test again?
 
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skyshrimp said:
What should I do with the silver afterwards?

Depends on the local regulations considering hazardous materials. In general, you should check what they are before trying any experiments.

Is it possible to turn it back into 5g of silver nitrate to redo the test again?

Yes and no. Yes, there are ways of recycling silver from the waste. No, you will never get exactly 100% back.

Question is if you can afford recycling - for small samples, with non-existing lab and zero experience, it will be much more costly than the recovered silver (if you will recover anything at all).
 
You could mix the silver chloride with about an equal amount of NaCl and grind it, adding little water until you get a fine paste. When you rub some copper object with it, you will depose a shiny sheet of silver on it.
 

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