Chromate and dichromate ions in equilibrium

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SUMMARY

The equilibrium between potassium dichromate (K2Cr2O7) and potassium chromate (K2CrO4) involves the presence of water in the dichromate ion equation but not in the chromate ion equation. This discrepancy arises from the stoichiometry of the reaction, where the dichromate ion includes water molecules, while the chromate ion balances with hydrogen cations (H+). Both potassium dichromate and potassium chromate are soluble in water, contradicting initial assumptions about their solubility affecting the equilibrium.

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Homework Statement

:-Why in equilibrium equation of potassium dichromate and chromate give below (in point 2.Relevant equations )there is H2O with dichromate ion but not with chromate ion, rather 2 hydrogen cation is present?[/B]

Homework Equations

dichreqm3.gif
[/B]

The Attempt at a Solution

:-I think it is something related with solubility .potassium Dichromate is soluble in water and potassium chromate is not.But i am not getting how this makes sense?Please help[/B]
 
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gracy said:
The attempt at a solution:-I think it is something related with solubility .
No.
gracy said:
potassium Dichromate is soluble in water and potassium chromate is not.
Both are water soluble. This won't get you anywhere.

Ignore the notes in red in the chemical equation and just look at the stoichiometry between the right and left hand sides, counting H, O, and water.
 

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