What is the mass of potassium nitrate which crystallizes?

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Discussion Overview

The discussion revolves around a homework problem involving the crystallization of potassium nitrate from a saturated solution when cooled from 68 to 36 degrees Celsius. Participants explore the calculations related to the mass of potassium nitrate that crystallizes based on solubility data at different temperatures.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Technical explanation

Main Points Raised

  • One participant presents a calculation to determine the mass of potassium nitrate in a 20g saturated solution at 68 degrees Celsius, concluding that it contains 10.9g of potassium nitrate.
  • Another participant questions the accuracy of the numbers used in the calculation, indicating that while the calculation method may be correct, the numerical values may not be.
  • A subsequent reply seeks clarification on which specific part of the calculation is incorrect.
  • Another participant corrects the mass of crystallized potassium nitrate to 4.64g based on their interpretation of the numbers.
  • One participant acknowledges a typo in their earlier calculation and expresses confusion over the discrepancy in their results.
  • Several participants discuss the relationship between the amount of dissolved nitrate and the water, noting that the ratio of nitrate to water decreases as the temperature changes, leading to a halving of the dissolved nitrate amount.

Areas of Agreement / Disagreement

Participants express differing views on the numerical accuracy of the calculations presented. There is no consensus on the correct values, and the discussion remains unresolved regarding the specific errors in the calculations.

Contextual Notes

Participants rely on solubility data at two different temperatures but do not clarify the assumptions made regarding the solution's composition or the method of calculation. There are also indications of potential typos affecting the results.

lioric
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Homework Statement


20g of saturated solution of potassium nitrate is cooled from 68 to 36 degree Celsius
What is the mass of potassium nitrate which crystallizes?
Potassium nitrate solubility per 100g of water
68 degree Celsius = 120g
38 degree Celsius = 60g

Homework Equations


I tried without equations just cross multiplying

The Attempt at a Solution


Please check if my answer is correct

Since the question says 20g of solution which means it's mass of potassium nitrate + water
So since
120g = 100g water = 220g solution (120+100)

120g = 220g
X = 20g
X= 10.9g of potassium nitrate in unknown amount of water

20-10.9= 9.1g of water

Therefore 20g of solution is actually 10.9g of potassium nitrate in 9.1g of water at 68 degree Celsius

In 38 degree Celsius = 60g potassium nitrate per 100 g of water

So
60g = 100g
X = 9.1g

X = 5.46g potassium nitrate in 38 degree Celsius in 9.1g water

Amount of potassium nitrate crystallized
10.9-5.46=5.44

Is this calculation correct?
 
Last edited:
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The calculation is. The numbers are not.
 
BvU said:
The calculation is. The numbers are not.

Numbers are not? Please do tell what I did wrong? Or at least tel me which part?
 
lioric said:
X= 10.9g of potassium nitrate
lioric said:
10.1-5.46=4.64g
 
Oh that's right it s a typo
Actually I was wondering why I got 4.5 while in my original working I got 5.4
I thought I made a calculation error
Thanks
And thank you for your time
 
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And of course the dissolved nitrate/water ratio drops by a factor of 2, the amount of water stays the same, so the amount of dissolved nitrate halves too...
 
BvU said:
And of course the dissolved nitrate/water ratio drops by a factor of 2, the amount of water stays the same, so the amount of dissolved nitrate halves too...

Could explain that part a bit more
 
120 g/100g water goes to 60 g/100 g water, so y g/x g water goes to ##1\over 2## y g/x g water.
 
BvU said:
120 g/100g water goes to 60 g/100 g water, so y g/x g water goes to ##1\over 2## y g/x g water.
Wow
Thank you very much
 

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