Comparing simulated dispersion relations to experimental Silicon data

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lylos
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I have three different plots for the dispersion relation of Silicon. How can I compare the two plots that I have generated to the plot of the experimental data? I remember that I had to do this last semester, but I don't remember what it was called.
 
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Ok, maybe finding the correlation coefficients for each plot may be my best bet in this situation. Anyone know?
 
Are there some parameters involved in the generated (non-experimental) plots? How about doing a least-squares fit where you adjust those parameters?